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. Author manuscript; available in PMC: 2017 Apr 4.
Published in final edited form as: Inorg Chem. 2016 Mar 14;55(7):3218–3228. doi: 10.1021/acs.inorgchem.5b02019

Figure 4.

Figure 4

(a) Plots of the amount of produced pentamethylbenzyl alcohol for photocatalytic oxygenation of HMB (0 – 4.0 × 10−2 M) by MnIII(TBP8Cz) (1.0 × 10−5 M) in the presence of HOTf(4.0 × 10−5 M) in an 02-saturated PhCN solution and (b) Plots of the amount of produced pentamethylbenzyl alcohol for photocatalytic oxygenation of HMB (2.0 × 10−2 M) by MnIII(TBP8Cz) (1.0 × 10−5 M) in the presence of HOTf (4.0 × 10−5 M) in a PhCN solution vs the oxygen concentration (0–8.5 × 10−3 M) under photoirradiation (white light) for 1 h at room temperature.