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. 2016 Apr 27;12:825–834. doi: 10.3762/bjoc.12.81

Table 4.

Intermolecular H···π and π–π interactions in the crystal of 6a.

graphic file with name Beilstein_J_Org_Chem-12-825-i001.jpg

C–H···π interactions

C–H···pln Dpln (Å) α (°) βpln (°)
C20–H20···C(13–18)a 2.93 116 85.8
C18–H18···C(19–24)b 2.95 109 78.7
C14–H14···C(5–10)a 2.79 143 39.5

π···π interactions

pln···pln d (Å) βpln (°)
C(4–12)···C(4–12)a 3.52 0 within s.d.
C(4–12)···C(4–12)b 3.56 0 within s.d.

aSymmetry equivalent atoms are given by −x, 1−y, −z. bSymmetry equivalent atoms are given by (ii) 1−x, 1−y, −z.