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. 2016 Apr 27;12:813–824. doi: 10.3762/bjoc.12.80

Table 2.

Dependence on the stoichiometric amount of propiophenone (1a) enolate with regard to the metal (reaction time: 2 h, reaction temperature: 25 °C, 5a/6a in %).

Entry Metal chloride Amount of propiophenone (1a)

2 equiv 3 equiv 4 equiv 6 equiv

5a 6a 5a 6a 5a 6a 5a 6a

1 ZrCl4 33 48 76 23 68 22 – –
2 SnCl4 20 45 14 35 36 22 – –
3 AlCl3 – – 66 8 – – 66 34
4 InCl3 – – 85 13 – – >99 –