Table 1. Optoelectronic properties of O-IDTBR and EH-IDTBR acceptors.
| ɛ (104 M−1 cm−1)* | λmax solution (nm)* | λmax film (nm)† | λmax ann. (nm)‡ | Eg opt. (eV)† | EA (eV)§ | IP (eV)|| | |
|---|---|---|---|---|---|---|---|
| O-IDTBR | 9.9±0.1 | 650 | 690 | 731 | 1.63±0.1 | 3.88±0.05 | 5.51±0.05 |
| EH-IDTBR | 10.3±0.1 | 650 | 673 | 675 | 1.68±0.1 | 3.90±0.05 | 5.58±0.05 |
EA, electron affinity; IP, ionization potential.
Measurements were carried out in:
*CHCl3 solution.
†Thin film spin-coated from 10 mg ml−1 chlorobenzene solution.
‡Thin film annealed at 130 °C for 10 min.
§Cyclic voltammetry carried out on the as-cast thin film with 0.1 M TBAPF6 electrolyte in acetonitrile.
||Estimated from the electrochemical EA and the optical Eg.