Table 4. Relevant solid-state photophysical data for complexes 1–3 .

Complex a	λ em  b (nm)	Φ PL  c (%)	τ e  d (μs)
1 (neat film)	520	62	0.41 (41%), 0.85 (59%)
1 (doped film)	518	90	1.75
2 (neat film)	508	54	0.39 (68%), 1.23 (34%)
2 (doped film)	474, 502	97	1.63
3 (neat film)	465, 492	43	0.19 (29%), 1.23 (71%)
3 (doped film)	462, 492	89	1.92

^aNeat films were dip coated from MeCN solution while doped films were dip coated from a DCM solution of 5 wt% of the complex in PMMA.

^b λ _exc at 360 nm.

^cMeasured using an integrating sphere, with λ _exc for the neat film performed at 360 nm and for the doped films at 300 nm.

^d λ _exc at 378 nm.