Table 3. Experimental details.
| Crystal data | |
| Chemical formula | [Ni(C16H14N3OS)2] |
| M r | 651.43 |
| Crystal system, space group | Monoclinic, P21/n |
| Temperature (K) | 297 |
| a, b, c (Å) | 10.220 (3), 15.468 (5), 19.151 (6) |
| β (°) | 92.150 (5) |
| V (Å3) | 3025.1 (17) |
| Z | 4 |
| Radiation type | Mo Kα |
| μ (mm−1) | 0.82 |
| Crystal size (mm) | 0.19 × 0.18 × 0.09 |
| Data collection | |
| Diffractometer | Bruker APEX DUO CCD area-detector |
| Absorption correction | Multi-scan (SADABS; Bruker, 2009 ▸) |
| No. of measured, independent and observed [I > 2σ(I)] reflections | 43914, 5893, 4635 |
| R int | 0.070 |
| (sin θ/λ)max (Å−1) | 0.617 |
| Refinement | |
| R[F 2 > 2σ(F 2)], wR(F 2), S | 0.048, 0.100, 1.05 |
| No. of reflections | 5893 |
| No. of parameters | 398 |
| H-atom treatment | H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) | 0.46, −0.38 |