Table 5.
Recovery in Flexfilm bag [%] |
Recovery in Kynar bag [%] |
Recovery in Tedlar bag [%] |
|||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
VOC | Vf[%] | 6 h | 24 h | 48 h | 72 h | 126 h | 168 h | 6 h | 24 h | 48 h | 72 h | 126 h | 168 h | 6 h | 24 h | 48 h | 72 h | 126 h | 168 h |
n-Butane | 20 | 180 | 424 | 714 | 1020 | 1621 | 1978 | 113 | 107 | 109 | 131 | 130 | 95 | 94 | 92 | 90 | 88 | 85 | |
40 | 159 | 296 | 454 | 607 | 963 | 0 | 93 | 94 | 89 | 85 | 86 | 84 | 93 | 95 | 94 | 91 | 94 | 81 | |
80 | 142 | 238 | 352 | 471 | 693 | 840 | 112 | 113 | 103 | 106 | 104 | 104 | 103 | 102 | 97 | 93 | 94 | 93 | |
n-Pentane | 20 | 120 | 176 | 210 | 296 | 412 | 486 | 94 | 91 | 91 | 84 | 82 | 92 | 93 | 89 | 85 | 79 | 76 | |
40 | 111 | 132 | 162 | 193 | 260 | 0 | 96 | 92 | 84 | 82 | 78 | 77 | 99 | 93 | 88 | 81 | 85 | 80 | |
80 | 98 | 113 | 137 | 154 | 170 | 205 | 112 | 106 | 105 | 98 | 96 | 90 | 102 | 100 | 91 | 86 | 86 | 81 | |
n-Hexane | 20 | 215 | 472 | 721 | 992 | 1448 | 1723 | 103 | 101 | 100 | 129 | 125 | 99 | 97 | 95 | 90 | 82 | 87 | |
40 | 179 | 347 | 528 | 673 | 1019 | 0 | 92 | 91 | 88 | 81 | 83 | 75 | 94 | 96 | 90 | 90 | 93 | 82 | |
80 | 152 | 263 | 387 | 495 | 729 | 855 | 111 | 114 | 107 | 103 | 103 | 107 | 106 | 104 | 95 | 94 | 96 | 92 | |
n-Octane | 20 | 95 | 89 | 81 | 78 | 69 | 67 | 91 | 86 | 83 | 74 | 75 | 99 | 91 | 89 | 86 | 82 | 78 | |
40 | 97 | 91 | 85 | 85 | 81 | 0 | 93 | 92 | 88 | 84 | 81 | 78 | 98 | 95 | 88 | 85 | 86 | 80 | |
80 | 93 | 92 | 89 | 84 | 80 | 80 | 108 | 107 | 102 | 102 | 98 | 84 | 98 | 91 | 91 | 87 | 86 | 82 | |
n-Decane | 20 | 82 | 71 | 59 | 50 | 56 | 40 | 95 | 78 | 73 | 64 | 57 | 86 | 78 | 69 | 57 | 50 | 50 | |
40 | 96 | 92 | 69 | 59 | 55 | 0 | 98 | 83 | 78 | 71 | 63 | 49 | 92 | 85 | 76 | 71 | 62 | 57 | |
80 | 106 | 92 | 83 | 70 | 62 | 56 | 102 | 91 | 94 | 87 | 85 | 76 | 100 | 92 | 89 | 85 | 84 | 70 | |
Isobutane | 20 | 96 | 88 | 88 | 95 | 96 | 99 | 90 | 93 | 79 | 92 | 86 | 107 | 100 | 86 | 83 | 86 | 84 | |
40 | 99 | 93 | 86 | 69 | 80 | 0 | 99 | 96 | 79 | 77 | 74 | 80 | 101 | 90 | 88 | 74 | 77 | 74 | |
80 | 89 | 88 | 69 | 72 | 75 | 74 | 100 | 85 | 85 | 82 | 76 | 89 | 98 | 99 | 82 | 84 | 87 | 80 | |
Pentane, 2-methyl- | 20 | 102 | 132 | 138 | 149 | 187 | 203 | 102 | 100 | 89 | 92 | 88 | 94 | 81 | 84 | 83 | 83 | 81 | |
40 | 91 | 92 | 98 | 95 | 104 | 0 | 101 | 98 | 93 | 84 | 88 | 83 | 89 | 92 | 82 | 85 | 85 | 72 | |
80 | 87 | 86 | 87 | 85 | 89 | 97 | 110 | 102 | 101 | 95 | 98 | 88 | 99 | 97 | 86 | 88 | 89 | 93 | |
Octane, 4-methyl- | 20 | 124 | 178 | 231 | 263 | 332 | 358 | 100 | 99 | 104 | 105 | 104 | 105 | 125 | 123 | 147 | 148 | 179 | |
40 | 110 | 140 | 162 | 166 | 222 | 0 | 98 | 103 | 93 | 105 | 103 | 108 | 91 | 101 | 112 | 110 | 125 | 107 | |
80 | 110 | 107 | 140 | 131 | 170 | 169 | 99 | 104 | 102 | 103 | 103 | 89 | 102 | 103 | 100 | 104 | 111 | 112 | |
2-Pentene, (E) | 20 | 94 | 93 | 83 | 80 | 82 | 81 | 88 | 75 | 63 | 48 | 37 | 89 | 93 | 88 | 84 | 83 | 81 | |
40 | 93 | 81 | 85 | 80 | 80 | 0 | 93 | 87 | 73 | 63 | 44 | 30 | 97 | 94 | 90 | 87 | 86 | 82 | |
80 | 89 | 84 | 87 | 85 | 85 | 82 | 109 | 105 | 97 | 88 | 72 | 58 | 98 | 95 | 89 | 88 | 87 | 78 | |
2-Pentene, (Z) | 20 | 103 | 94 | 85 | 96 | 82 | 80 | 85 | 77 | 64 | 53 | 41 | 91 | 93 | 90 | 84 | 82 | 80 | |
40 | 113 | 105 | 104 | 99 | 104 | 93 | 90 | 75 | 66 | 50 | 36 | 96 | 92 | 91 | 85 | 84 | 83 | ||
80 | 94 | 88 | 93 | 88 | 88 | 85 | 109 | 105 | 95 | 89 | 76 | 65 | 99 | 93 | 89 | 89 | 87 | 82 | |
1-Hexene | 20 | 96 | 127 | 154 | 172 | 253 | 285 | 99 | 88 | 77 | 78 | 75 | 96 | 92 | 89 | 85 | 83 | 80 | |
40 | 99 | 112 | 129 | 138 | 173 | 94 | 88 | 85 | 76 | 74 | 68 | 92 | 91 | 84 | 87 | 88 | 80 | ||
80 | 97 | 103 | 111 | 115 | 135 | 145 | 111 | 107 | 101 | 96 | 93 | 88 | 97 | 94 | 83 | 85 | 81 | 84 | |
Isoprene | 20 | 93 | 87 | 80 | 70 | 70 | 65 | 85 | 77 | 69 | 57 | 47 | 88 | 90 | 86 | 82 | 79 | 77 | |
40 | 95 | 83 | 83 | 77 | 77 | 93 | 88 | 76 | 71 | 60 | 50 | 97 | 92 | 89 | 86 | 84 | 81 | ||
80 | 91 | 86 | 87 | 83 | 80 | 77 | 109 | 105 | 98 | 92 | 83 | 75 | 101 | 102 | 93 | 94 | 96 | 89 | |
Benzene | 20 | 85 | 80 | 69 | 65 | 58 | 53 | 90 | 77 | 63 | 54 | 54 | 92 | 85 | 79 | 74 | 68 | 65 | |
40 | 93 | 86 | 82 | 71 | 71 | 88 | 80 | 71 | 65 | 61 | 56 | 88 | 86 | 79 | 77 | 74 | 69 | ||
80 | 93 | 87 | 83 | 73 | 76 | 70 | 105 | 99 | 91 | 84 | 81 | 70 | 97 | 91 | 82 | 79 | 81 | 79 | |
Toluene | 20 | 85 | 78 | 67 | 61 | 56 | 51 | 81 | 66 | 60 | 52 | 46 | 90 | 81 | 73 | 64 | 59 | 55 | |
40 | 87 | 84 | 79 | 70 | 66 | 88 | 79 | 71 | 63 | 56 | 52 | 90 | 84 | 78 | 72 | 66 | 62 | ||
80 | 92 | 88 | 82 | 77 | 73 | 67 | 100 | 94 | 85 | 78 | 70 | 64 | 95 | 91 | 85 | 82 | 78 | 73 | |
p-Xylene | 20 | 80 | 72 | 55 | 49 | 42 | 40 | 71 | 55 | 48 | 40 | 39 | 84 | 69 | 64 | 52 | 45 | 43 | |
40 | 89 | 78 | 74 | 63 | 63 | 0 | 76 | 69 | 56 | 51 | 48 | 38 | 87 | 79 | 68 | 62 | 59 | 53 | |
80 | 86 | 83 | 76 | 70 | 64 | 52 | 94 | 84 | 73 | 68 | 58 | 49 | 91 | 88 | 82 | 76 | 72 | 67 | |
Acetone | 20 | 95 | 95 | 92 | 94 | 92 | 90 | 71 | 58 | 53 | 39 | 37 | 89 | 79 | 71 | 65 | 55 | 52 | |
40 | 90 | 93 | 90 | 89 | 92 | 73 | 59 | 47 | 43 | 32 | 26 | 90 | 82 | 77 | 72 | 67 | 61 | ||
80 | 94 | 91 | 91 | 88 | 86 | 86 | 97 | 82 | 70 | 62 | 51 | 39 | 103 | 97 | 92 | 88 | 84 | 81 | |
2-Butanone | 20 | 123 | 133 | 158 | 210 | 217 | 228 | 87 | 80 | 80 | 72 | 71 | 89 | 79 | 76 | 69 | 55 | 56 | |
40 | 121 | 139 | 155 | 152 | 226 | 82 | 72 | 60 | 60 | 56 | 52 | 102 | 96 | 89 | 83 | 77 | 65 | ||
80 | 105 | 122 | 131 | 123 | 140 | 163 | 103 | 83 | 81 | 74 | 67 | 62 | 99 | 92 | 86 | 85 | 79 | 76 | |
2-Pentanone | 20 | 86 | 74 | 65 | 60 | 55 | 47 | 64 | 42 | 34 | 24 | 20 | 89 | 78 | 65 | 61 | 55 | 47 | |
40 | 89 | 86 | 79 | 75 | 70 | 71 | 53 | 40 | 33 | 23 | 19 | 91 | 82 | 72 | 70 | 65 | 59 | ||
80 | 94 | 92 | 81 | 82 | 76 | 70 | 96 | 78 | 59 | 54 | 43 | 36 | 100 | 93 | 84 | 78 | 81 | 77 | |
4-Heptanone | 20 | 86 | 65 | 51 | 42 | 29 | 26 | 42 | 27 | 22 | 10 | 12 | 82 | 64 | 55 | 51 | 38 | 31 | |
40 | 87 | 78 | 66 | 60 | 51 | 59 | 38 | 26 | 20 | 16 | 13 | 89 | 73 | 69 | 60 | 55 | 49 | ||
80 | 92 | 87 | 85 | 68 | 60 | 53 | 82 | 60 | 44 | 38 | 24 | 21 | 100 | 83 | 86 | 80 | 76 | 70 | |
Propanal | 20 | 132 | 174 | 208 | 233 | 278 | 299 | 84 | 75 | 75 | 71 | 67 | 96 | 86 | 83 | 76 | 70 | 67 | |
40 | 118 | 154 | 175 | 194 | 239 | 85 | 78 | 76 | 71 | 66 | 66 | 94 | 89 | 83 | 80 | 76 | 71 | ||
80 | 108 | 121 | 134 | 142 | 156 | 166 | 109 | 98 | 90 | 91 | 85 | 75 | 99 | 93 | 87 | 85 | 81 | 81 | |
Hexanal | 20 | 104 | 86 | 121 | 139 | 125 | 145 | 72 | 130 | 115 | 98 | 92 | 101 | 100 | 95 | 94 | 91 | 85 | |
40 | 103 | 101 | 135 | 114 | 129 | 92 | 78 | 78 | 73 | 72 | 72 | 103 | 101 | 98 | 95 | 93 | 91 | ||
80 | 100 | 107 | 123 | 98 | 76 | 126 | 155 | 140 | 115 | 126 | 110 | 125 | 99 | 98 | 99 | 103 | 88 | 95 | |
Octanal | 20 | 101 | 95 | 96 | 80 | 65 | 82 | 72 | 63 | 54 | 45 | 61 | 98 | 66 | 69 | 45 | 50 | 51 | |
40 | 113 | 85 | 87 | 109 | 80 | 79 | 45 | 63 | 52 | 40 | 51 | 83 | 87 | 85 | 61 | 55 | 50 | ||
80 | 132 | 99 | 95 | 90 | 85 | 89 | 110 | 93 | 86 | 80 | 53 | 53 | 101 | 88 | 77 | 64 | 64 | 52 | |
Furan | 20 | 93 | 97 | 97 | 100 | 106 | 107 | 85 | 70 | 60 | 46 | 37 | 86 | 86 | 79 | 75 | 70 | 64 | |
40 | 90 | 97 | 99 | 102 | 111 | 86 | 81 | 74 | 63 | 54 | 47 | 93 | 87 | 84 | 79 | 76 | 71 | ||
80 | 98 | 94 | 92 | 92 | 92 | 92 | 107 | 101 | 93 | 87 | 78 | 67 | 97 | 93 | 88 | 86 | 84 | 81 | |
Furan, 2-methyl- | 20 | 88 | 76 | 70 | 65 | 58 | 53 | 77 | 59 | 49 | 34 | 27 | 93 | 82 | 76 | 71 | 66 | 62 | |
40 | 92 | 88 | 83 | 80 | 78 | 87 | 74 | 65 | 56 | 42 | 34 | 103 | 96 | 90 | 83 | 81 | 76 | ||
80 | 95 | 89 | 84 | 79 | 76 | 73 | 106 | 89 | 87 | 76 | 65 | 56 | 97 | 87 | 78 | 84 | 81 | 78 | |
Furan, 2,5-dimethyl- | 20 | 89 | 74 | 57 | 44 | 29 | 22 | 66 | 42 | 26 | 12 | 7 | 91 | 80 | 67 | 62 | 54 | 47 | |
40 | 86 | 81 | 68 | 58 | 46 | 86 | 68 | 47 | 29 | 13 | 6 | 96 | 86 | 75 | 72 | 66 | 59 | ||
80 | 99 | 91 | 82 | 77 | 67 | 59 | 106 | 93 | 72 | 59 | 37 | 22 | 101 | 92 | 82 | 77 | 79 | 72 | |
Methyl acetate | 20 | 89 | 86 | 79 | 68 | 73 | 71 | 65 | 53 | 47 | 42 | 44 | 81 | 79 | 68 | 64 | 57 | 53 | |
40 | 94 | 88 | 83 | 79 | 81 | 71 | 61 | 50 | 41 | 29 | 22 | 92 | 85 | 79 | 74 | 67 | 63 | ||
80 | 93 | 88 | 86 | 84 | 80 | 72 | 99 | 85 | 72 | 63 | 47 | 38 | 99 | 92 | 87 | 84 | 80 | 77 | |
Ethyl acetate | 20 | 91 | 80 | 67 | 66 | 54 | 48 | 70 | 54 | 47 | 34 | 29 | 89 | 80 | 73 | 67 | 58 | 53 | |
40 | 89 | 76 | 74 | 71 | 69 | 79 | 57 | 54 | 46 | 37 | 32 | 100 | 94 | 87 | 79 | 74 | 67 | ||
80 | 93 | 84 | 87 | 78 | 77 | 71 | 100 | 87 | 76 | 67 | 58 | 52 | 98 | 93 | 83 | 84 | 80 | 78 | |
n-Butyl acetate | 20 | 84 | 82 | 66 | 64 | 52 | 59 | 71 | 59 | 51 | 45 | 38 | 86 | 78 | 69 | 57 | 50 | 50 | |
40 | 92 | 86 | 81 | 75 | 64 | 82 | 69 | 60 | 52 | 43 | 39 | 92 | 85 | 76 | 71 | 62 | 57 | ||
80 | 93 | 89 | 82 | 78 | 72 | 69 | 97 | 83 | 69 | 64 | 53 | 41 | 101 | 93 | 86 | 82 | 79 | 73 | |
Dimethyl sulfide | 20 | 87 | 73 | 59 | 50 | 36 | 30 | 69 | 45 | 30 | 16 | 9 | 90 | 86 | 80 | 73 | 67 | 61 | |
40 | 88 | 76 | 63 | 55 | 46 | 80 | 75 | 63 | 50 | 39 | 31 | 89 | 86 | 80 | 77 | 71 | 69 | ||
80 | 93 | 83 | 78 | 73 | 65 | 61 | 104 | 95 | 85 | 76 | 63 | 55 | 97 | 89 | 85 | 84 | 82 | 79 | |
Methyl propyl sulfide | 20 | 89 | 76 | 64 | 56 | 44 | 37 | 73 | 47 | 31 | 14 | 7 | 93 | 83 | 79 | 73 | 65 | 59 | |
40 | 86 | 84 | 75 | 66 | 58 | 85 | 74 | 59 | 48 | 35 | 25 | 91 | 88 | 82 | 76 | 73 | 69 | ||
80 | 95 | 89 | 77 | 77 | 68 | 66 | 104 | 96 | 79 | 73 | 60 | 52 | 95 | 91 | 85 | 84 | 81 | 78 | |
Thiophene | 20 | 77 | 70 | 58 | 54 | 45 | 40 | 75 | 61 | 52 | 39 | 31 | 86 | 76 | 65 | 59 | 50 | 47 | |
40 | 82 | 79 | 73 | 65 | 60 | 83 | 72 | 63 | 55 | 46 | 40 | 87 | 80 | 74 | 68 | 62 | 51 | ||
80 | 86 | 84 | 78 | 74 | 68 | 62 | 101 | 93 | 84 | 77 | 68 | 62 | 99 | 100 | 82 | 84 | 79 | 80 | |
Thiophene, 3-methyl- | 20 | 73 | 56 | 43 | 38 | 29 | 24 | 64 | 45 | 37 | 27 | 20 | 83 | 66 | 55 | 48 | 39 | 34 | |
40 | 83 | 71 | 60 | 53 | 42 | 77 | 61 | 50 | 42 | 33 | 27 | 86 | 75 | 65 | 59 | 52 | 46 | ||
80 | 89 | 78 | 71 | 64 | 57 | 51 | 96 | 83 | 71 | 63 | 52 | 46 | 99 | 93 | 85 | 80 | 74 | 69 | |
(+)-3-Carene | 20 | 85 | 71 | 61 | 54 | 42 | 37 | 88 | 84 | 58 | 48 | 42 | 83 | 84 | 80 | 71 | 57 | 60 | |
40 | 97 | 89 | 88 | 76 | 67 | 92 | 80 | 79 | 64 | 46 | 36 | 94 | 91 | 95 | 85 | 77 | 62 | ||
80 | 104 | 98 | 93 | 80 | 68 | 66 | 91 | 92 | 91 | 84 | 76 | 69 | 93 | 82 | 88 | 83 | 76 | 67 | |
α-Pinene | 20 | 93 | 82 | 78 | 68 | 58 | 60 | 101 | 95 | 75 | 65 | 57 | 99 | 87 | 84 | 85 | 81 | 88 | |
40 | 86 | 89 | 77 | 76 | 70 | 99 | 90 | 86 | 80 | 67 | 56 | 93 | 95 | 92 | 87 | 84 | 78 | ||
80 | 99 | 81 | 92 | 82 | 86 | 81 | 115 | 103 | 107 | 100 | 83 | 75 | 101 | 99 | 90 | 94 | 89 | 88 | |
p-Cymene | 20 | 77 | 59 | 45 | 38 | 29 | 27 | 67 | 50 | 40 | 34 | 26 | 83 | 75 | 63 | 56 | 44 | 43 | |
40 | 85 | 77 | 67 | 58 | 50 | 79 | 65 | 54 | 48 | 39 | 30 | 93 | 87 | 75 | 67 | 63 | 51 | ||
80 | 98 | 87 | 78 | 68 | 59 | 54 | 89 | 76 | 69 | 63 | 52 | 46 | 98 | 93 | 85 | 81 | 78 | 63 | |
D-Limonene | 20 | 82 | 67 | 57 | 51 | 39 | 41 | 79 | 60 | 50 | 36 | 30 | 81 | 82 | 75 | 70 | 54 | 53 | |
40 | 87 | 83 | 75 | 71 | 58 | 86 | 77 | 63 | 54 | 39 | 28 | 96 | 92 | 75 | 80 | 71 | 59 | ||
80 | 107 | 98 | 90 | 82 | 68 | 66 | 99 | 79 | 82 | 76 | 54 | 41 | 103 | 100 | 95 | 92 | 86 | 69 | |
Eucalyptol | 20 | 81 | 86 | 70 | 33 | 29 | 36 | 80 | 69 | 63 | 57 | 58 | 96 | 125 | 138 | 142 | 123 | 122 | |
40 | 74 | 82 | 71 | 65 | 63 | 91 | 86 | 80 | 83 | 75 | 87 | 106 | 108 | 113 | 111 | 109 | 88 | ||
80 | 112 | 107 | 95 | 101 | 90 | 84 | 105 | 96 | 94 | 102 | 87 | 82 | 98 | 97 | 102 | 101 | 102 | 85 | |
Ethyl ether | 20 | 94 | 89 | 82 | 70 | 73 | 69 | 86 | 82 | 79 | 72 | 67 | 88 | 90 | 88 | 85 | 82 | 78 | |
40 | 96 | 86 | 83 | 80 | 78 | 94 | 90 | 84 | 83 | 76 | 73 | 96 | 92 | 89 | 85 | 87 | 81 | ||
80 | 88 | 86 | 88 | 84 | 80 | 79 | 106 | 103 | 98 | 93 | 91 | 87 | 94 | 90 | 89 | 87 | 86 | 79 | |
Acetonitrile | 20 | 47 | 31 | 27 | 34 | 22 | 17 | 57 | 34 | 31 | 12 | 7 | 57 | 38 | 27 | 24 | 16 | 11 | |
40 | 69 | 42 | 27 | 32 | 24 | 45 | 26 | 18 | 12 | 8 | 2 | 64 | 47 | 38 | 31 | 23 | 17 | ||
80 | 74 | 50 | 43 | 36 | 27 | 28 | 66 | 39 | 22 | 12 | 4 | 6 | 87 | 65 | 56 | 49 | 38 | 33 | |
Dimethyl selenide | 20 | 79 | 65 | 46 | 44 | 30 | 26 | 37 | 12 | 4 | 2 | 1 | 89 | 77 | 65 | 51 | 40 | 31 | |
40 | 82 | 64 | 54 | 45 | 37 | 78 | 53 | 29 | 17 | 7 | 3 | 96 | 86 | 76 | 64 | 61 | 48 | ||
80 | 87 | 81 | 73 | 71 | 64 | 59 | 96 | 74 | 55 | 40 | 23 | 15 | 96 | 89 | 84 | 78 | 73 | 66 | |
Pyrimidine | 20 | 45 | 26 | 18 | 18 | 12 | 10 | 47 | 27 | 25 | 14 | 13 | 53 | 31 | 21 | 16 | 11 | 10 | |
40 | 52 | 40 | 30 | 24 | 17 | 36 | 19 | 13 | 11 | 6 | 5 | 65 | 42 | 29 | 25 | 17 | 14 | ||
80 | 80 | 58 | 42 | 38 | 30 | 25 | 56 | 33 | 17 | 17 | 10 | 8 | 82 | 66 | 50 | 42 | 32 | 28 |