Table 2. Experimental details.
| Crystal data | |
| Chemical formula | [Ag2(C3H6N2S)4(C18H15P)2](C2H3O2)2·[Ag(C2H3O2)(C3H6N2S)(C18H15P)2]2·2C2H3N·4H2O |
| M r | 3008.39 |
| Crystal system, space group | Triclinic, P
|
| Temperature (K) | 100 |
| a, b, c (Å) | 9.5867 (4), 16.3018 (7), 22.8548 (10) |
| α, β, γ (°) | 104.179 (2), 94.449 (2), 91.992 (2) |
| V (Å3) | 3447.2 (3) |
| Z | 1 |
| Radiation type | Mo Kα |
| μ (mm−1) | 0.78 |
| Crystal size (mm) | 0.16 × 0.15 × 0.13 |
| Data collection | |
| Diffractometer | Bruker AXS D8 Quest CMOS |
| Absorption correction | Multi-scan (SADABS; Bruker, 2014 ▸) |
| T min, T max | 0.882, 0.903 |
| No. of measured, independent and observed [I > 2σ(I)] reflections | 71762, 20957, 18898 |
| R int | 0.026 |
| (sin θ/λ)max (Å−1) | 0.716 |
| Refinement | |
| R[F 2 > 2σ(F 2)], wR(F 2), S | 0.042, 0.088, 1.26 |
| No. of reflections | 20957 |
| No. of parameters | 826 |
| No. of restraints | 6 |
| H-atom treatment | H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) | 1.05, −0.97 |