Skip to main content
. 2015 Aug 7;6:7992. doi: 10.1038/ncomms8992

Figure 4. Understanding the structure of the active sites.

Figure 4

(a) Comparison of the HER activity of the CoNPs/CoNx/C and CoNx/C catalysts showing the influence of acid leaching. Insets are TEM images demonstrating that all cobalt particles were removed by acid leaching. (b) HER polarization plots of CoNx/C with and without 10 mM KSCN in 0.5 M H2SO4, indicating that SCN ions strongly poison the CoNx/C catalyst. Insets are illustrations of cobalt centres blocked by the SCN ions. These measurements indicated that the cobalt is involved in the active centers but not in the form of metallic nanoparticles.