TABLE 1.
Soil | pHb | Total organic carbon (mg g−1)c | Freundlich parameters for adsorption of 2,4-dichlorophenold
|
||
---|---|---|---|---|---|
Kf | n | KOC | |||
Nonplanted | 4.03 (0.007) | 24.61 (0.80) | 5.75 (1.02) | 0.83 (0.006) | 233.6 |
L. perenne rhizosphere | 4.02 (0.003) | 21.03 (0.51) | 5.60 (1.02) | 0.82 (0.007) | 266.3 |
T. pratense rhizosphere | 4.04 (0.008) | 24.52 (0.71) | 5.47 (1.01) | 0.83 (0.005) | 223.1 |
Soil was sampled from the rhizospheres of L. perenne and T. pratense after 60 days of plant growth. Values are means (standard errors), n = 4.
Determined in CaCl2 after removal of root debris.
Determined by wet oxidation after removal of root debris.
The concentration dependence of 2,4-dichlorophenol adsorption to L. perenne, T. pratense (with incorporated root debris), and nonplanted soil was investigated after 1 h (25°C) over triplicate initial aqueous concentrations of 0.2, 2, 10, 50, and 250 μg of [14C]2,4-dichlorophenol ml−1. Data are expressed as the linear form of the Freundlich equation (r2 > 0.99 in all cases), logS = logKf + nlogA, where S is the adsorbed concentration (in micrograms per gram), A is the aqueous concentration (in micrograms per milliliter), logKf is the intercept, and n is the elasticity of sorption. Koc is calculated as Kf/percent total organic carbon × 100.