. Author manuscript; available in PMC: 2016 Oct 16.

Published in final edited form as: J Org Chem. 2015 Sep 29;80(20):9989–9999. doi: 10.1021/acs.joc.5b01558

Table 3.

Scope of Stannanes with Thioesters 1a and 1b

entry	thioester	stannane	yield
1	1a	2a	97%
2	1b	2a	95%
3	1a		88%
4	1b	2b	81%
5	1a		96%
6	1b	2c	89%
7	1a		66%
8	1b	2d	67%
9	1a		81%
10	1b	2e	78%
11	1a		81%
12	1b	2f	71%
13	1a		78%
14	1b	2g	72%

Standard conditions: 1 (0.1 mmol), 2 (2.0 equiv), CuOAc (2.0 equiv), THF (0.1 M) mixed under argon at 50 °C.

R = 4-MeOC₆H₄

entry	thioester	stannane	yield
1	1a	2a	97%
2	1b	2a	95%
3	1a		88%
4	1b	2b	81%
5	1a		96%
6	1b	2c	89%
7	1a		66%
8	1b	2d	67%
9	1a		81%
10	1b	2e	78%
11	1a		81%
12	1b	2f	71%
13	1a		78%
14	1b	2g	72%

entry	thioester	stannane	yield
1	1a	2a	97%
2	1b	2a	95%
3	1a		88%
4	1b	2b	81%
5	1a		96%
6	1b	2c	89%
7	1a		66%
8	1b	2d	67%
9	1a		81%
10	1b	2e	78%
11	1a		81%
12	1b	2f	71%
13	1a		78%
14	1b	2g	72%

entry	thioester	stannane	yield
1	1a	2a	97%
2	1b	2a	95%
3	1a		88%
4	1b	2b	81%
5	1a		96%
6	1b	2c	89%
7	1a		66%
8	1b	2d	67%
9	1a		81%
10	1b	2e	78%
11	1a		81%
12	1b	2f	71%
13	1a		78%
14	1b	2g	72%