Table 13.

Integrated intensities and transition moments for N₂O

				Used in Atlas Calculation
Band	Frequency interval	Measured integrated intensity	Ref.	Integrated intensity		Transition momenta
	(cm−1)	(cm−2 atm−1)c		(cm−2 atm1)	(cm/molecule) ×1019	${\left|R_{v^{″}{l}^{″}}^{v^{\prime }{l}^{\prime }}\right|}^{\mathrm{b}}$ (D)d
		at 296 K		at 296 K
v2	520–660	28.9(15)e,f	[5.214]	24.5	9.88	0.0692
		30.4(40)f	[5.151]	29.2f
		31.4(40)f	[5.157]
v1 – v3	880–990	0.0524	[5.209]	0.052	0.021	0.056
		0.055	[5.172]
v1 – 2v2	990–1090	–	–	0.01	0.004	0.018
2v2	1110–1225	7.00(3)	[5.218]	6.66	2.69	0.0247
		7.36(7)	[5.216]	8.30f
		6.98	[5.237]
		8.27(43)f	[5.214]
		8.49(9)f	[5.234]
v3	1200–1340	207.(1)	[5.218]	206.	83.1	0.1326
		225.(12)f	[5.214]	232.5f
		226.(2)f	[5.234]
		229.8(45)	[5.216]
v2 + v3	1835–1925	0.52(3)	[5.212]	0.52	0.21	0.00548
		0.58(10)f	[5.214]	0.60f
		0.437(20)	[5.185]
v1	2140–2269	1207.(22)	[5.226]	1206.	486.4	0.244
		1421.(76)f	[5.214]	1358.f
		1189.(30)	[5.187]
		1302.(50)	[5.171]
		1301.(54)f	[5.198]
2v2 + v3	2410–2510	6.79(4)	[5.216]	6.7	27	0.017
		7.35(38)f	[5.214]	8.2f
2v3	2490–2605	30.86(14)	[5.216]	32.1	12.9	0.037
		32.1(17)f	[5.214]	36.3f
v1 + v2	2725–2840	2.24(13)f	[5.214]	1.895	0.764	0.0086
		2.11	[5.235]	2.26f

^aUnless indicated otherwise (see footnote f), the integrated intensities are given only for the vibrational transition from the ground state.

^bSee Eq. (3.24) for definition of $\left|R_{v^{″}{l}^{″}}^{v^{\prime }{l}^{\prime }}\right|$.

^c1 cm⁻² atm⁻¹ at 296 K = 4.0335 × 10⁻²⁰ cm/molecule.

^d1D = 3.336 × 10⁻³⁰ C m.

^eThe uncertainties in the last digits are given in parentheses.

^fAll hot bands and isotopes are included.