Table 5.
Rovibrational constants (in cm−1) used for 16O12C32S
| Vib. state | v0 | Bv | Dv.× 1011 | Hv×1014 | Lv×1017 |
|---|---|---|---|---|---|
| 0000 | 0.0 | 0.202 856 740 8(8)a | 4.340 64(25) | −0.329(30) | |
| 0110 | 520.422 055(147) | 0.203 209 834 8(21) | 4.411 48(31) | −0.260(38) | |
| 0001 | 858.966 932(48) | 0.202 251 831 6(60) | 4.433 50(36) | 0.045(45) | |
| 0220 | 1041.293 318(239) | 0.203 559 482 1(89) | 4.483 28(93) | −0.135(80) | |
| 0200 | 1047.042 048(11) | 0.203 480 485(12) | 4.419 64(63) | −0.712(73) | |
| 0111 | 1372.459 242(136) | 0.202 657 042(22) | 4.542 71(63) | [0.1]b | |
| 0330 | [1562.611 159] | 0.203 905 589 7(148) | 4.550 22(80) | [−0.3] | |
| 0310 | 1573.366 413(158) | 0.203 762 735 1(132) | 4.453 60(113) | −0.801(206) | |
| 0002 | 1710.976 247(76) | 0.201 635 352(32) | 4.533 64(111) | 0.396(102) | |
| 0221 | 1886.947 787(135) | 0.203 048 230 7(117) | 4.639 14(113) | [0.1] | |
| 0201 | 1892.230 557(91) | 0.202 953 496 6(220) | 4.554 09(123) | [−0.3] | |
| 1000 | 2062.200 841(121) | 0.201 641 530 0(477) | 4.409 80(260) | 4.551(470) | −0.1155(267) |
| 0440 | [2084.378 374] | 0.204 248 031 9(608) | 4.592 0(296) | [−0.3] | |
| 0420 | 2099.524 648(251) | 0.204 051 914 6(232) | 4.494 89(828) | [−0.6] | |
| 0400 | 2104.827 673(87) | 0.203 968 086 4(171) | 4.306 15(970) | −32.73(814) | |
| 0112 | 2218.028 446(175) | 0.202 091 366 5(527) | 4.682 71(123) | [0.6] | |
| 0331 | [2402.340 630] | 0.203 428 111(148) | 4.734 93(580) | [0.1] | |
| 0311 | 2412.122 352(193) | 0.203 259 077 6(203) | 4399 03(43) | [−0.3] | |
| 0003 | 2555.991 217(126) | 0.201 006 219(100) | 4.647 60(514) | 1.61(70) | |
| 111O | 2575.307 586(181) | 0.202 015 427(45) | 4.473 84(210) | 2.86(28) | |
| 0550 | [2606.596 100] | [0.204 589 3] | [4.55] | [−0.3] | |
| 0530 | 2625.607 054(200) | 0.204 345 249(246) | 4.583 7(402) | [−0.7] | |
| 0510 | 2635.589 700(206) | 0.204 198 969(125) | 4.387 40(643) | [−0.9] | |
| 0222 | [2726.564 984] | [0.202 523 2] | [4.804 7] | [0.1] | |
| 0202 | 2731.399 122(245) | 0.202 414 701(227) | 4.707(109) | [−0.3] | |
| 1001 | 2918.104 865(255) | 0.201 102 979(109) | 5.071 51(681) | 54.42(147) | −1.988(95) |
| 0441 | [2918.572 190] | [0.203 799 95] | [4.34] | [−0.3] | |
| 0421 | 2932.216 820(310) | 0.203 569 074(81) | 4.668 2(13) | [−0.3] | |
| 0401 | 2937.146 843(207) | 0.203 436 472(357) | 3.943 2(255) | −52.44(634) | 1.71(50) |
| 0113 | 3057.093 032(518) | 0.201 510 88(145) | 4.824(81) | [2.2] | |
| 1220 | [3088.908 46] | 0202 382 585(146) | 4.531 9(48) | [2.2] | |
| 1200 | 3095.554 42(9) | 0.202 311 240(147) | 4.500 9(56) | [2.2] | |
| 0332 | [3236.415 907] | [0.202 936 096] | [4.776 6] | [−0.2416] | |
| 0312 | 3245.260 572(251) | 0.202 744 75(42) | 4.771 0(128) | [−0.2416] | |
| 0004 | 3393.969 128(594) | 0.200 363 45(173) | 4.792(96) | [2.5] | |
| 1111 | 3424.139 675(235) | 0.201 515 951(235) | 4.757 4(105) | 8.78(125) | |
| 0223 | [3560.106 489] | [0.201 981 318] | [4.983 28] | [2.397] | |
| 0203 | 3564.479 808(987) | 0.201 863 71(335) | 4.989(220) | [2.397] | |
| 1330 | [3603.006 802] | [0.202 745 521] | [4.41] | [−1.948] | |
| 1310 | 3615.345 30(20) | 0.202 617 950(637) | 4.569(66) | 6.7(189) | |
| 0402c | 3762.825 61(83) | 0.202 601 23(931) | 15.06(323) | −5459.(4814) | 160.(3450) |
| 1002d | 3768.497 40(22) | 0.200 840 86(229) | −14.315(842) | −3551.(1249) | 9138.(864) |
| 1221 | 3931.301 568(234) | 0.201 923 654(440) | 4.782 5(153) | [6.00] | |
| 1201 | 3937.427 356(330) | 0.201 835 302(539) | 4.745 3(180) | [6.00] | |
| 1112 | 4266.325 10(53) | 0.201 069 31(120) | 6.539 9(551) | [240.0] |
a
The uncertainty in the last digits (twice the estimated standard error) is given in parentheses.
b
The values enclosed in square brackets were fixed during the analysis.
c
Additional terms needed in the analysis were: M = −1.03(118) × 10−17 and N =4.26(153) × 10−21. See Rcf. [5.132] for discussion of analysis beyond J = 50.
d
Additional terms needed in the analysis were: M = −3.21(28) × 10−17 and N =3.34(33) × 10−21.