Table 2.
Kinetic studies of chlorpyrifos degradation in various microbiologically active soils. The initial chlorpyrifos concentration was 200 mg kg−1 soil.
Soil treatment | Regression equation | Δk (d−1)A | ΔV (mg kg−1 d−1)B | T1/2 (d)D | R2C |
---|---|---|---|---|---|
SS | ln(Ct/C0) = −0.004t − 0.015 | 0.0053a | 0.84a | 130.7l | 0.983 |
nSS | ln(Ct/C0) = −0.013t + 0.025 | 0.0111b | 2.01b | 62.45k | 0.985 |
PS | ln(Ct/C0) = −0.016t + 0.042 | 0.0128a | 2.27a | 54.15d | 0.982 |
SS + JCp4 | ln(Ct/C0) = −0.063t + 0.231 | 0.0517e | 4.57h | 12.93e | 0.941 |
nSS + JCp4 | ln(Ct/C0) = −0.089t + 0.257 | 0.0688i | 4.76j | 10.07a | 0.922 |
PS + JCp4 | ln(Ct/C0) = −0.092t + 0.194 | 0.088c | 5.69b | 7.86a | 0.944 |
SS + FCp1 | ln(Ct/C0) = −0.058t + 0.159 | 0.0476g | 4.40g | 14.56f | 0.953 |
nSS + FCp1 | ln(Ct/C0) = −0.078t + 0.173 | 0.064h | 4.76j | 10.83b | 0.972 |
PS + FCp1 | ln(Ct/C0) = −0.076t + 0.141 | 0.079b | 5.69b | 8.77c | 0.962 |
SS, sterilized soil; nSS, non-sterilized soil; PS, planted soil; +, inoculated with.
Linear equation between ln(Ct/C0) of chemical data and time yielded regression equation and regression coefficient (R2).
Degradation rate constant (k) calculated using Ct = C0 × e−kt. Ct residual concentration of CP (mg kg−1).
Chlorpyrifos disappearance rate.
Disappearance time calculated by T1/2 = ln 2/k.