Table 6.
1H and 13C NMR spectral data for compounds 6, 7, and 8
| Position | 6
|
7
|
8
|
|||
|---|---|---|---|---|---|---|
| δH | δC | δH | δC | δH | δC | |
| 2 | 7.5, d(8) | 124.6, d | 7.3, br d | 123.0, d | 7.3, br d | 130.0, d |
| 3 | 6.8, br d | 113.5, d | 5.3, br d | 113.5, d | 6.7, br d | 101.1, d |
| 3a | 149.0, s | 156.7, s | 148.7, s | |||
| 5 | 7.9, br d | 127.5, d | 7.0, br d | 123.3, d | 7.6, d(5.2) | 147.4, d |
| 6 | 7.3, br d | 118.3, d | 6.8, br d | 118.9, d | 6.9, d(5.2) | 113.3, d |
| 6a | 136.8, s | 148.9, s | 135.7, s | |||
| 7 | 6.8, s | 100.5, d | 6.8, s | 100.6, d | 6.8, s | 99.7, d |
| 8 | 156.7, s | 156.9, s | 153.8, s | |||
| 9 | 134.6, s | 136.6, s | 135.0, s | |||
| 9a | 118.5, s | 134.4, s | 125.1, s | |||
| 9b | 100.9, s | 118.2, s | 117.6, s | |||
| NCH3 | 3.9, s | 45.2, q | 3.9, s | 45.1, q | 3.9, s | 45.3, q |
| OCH3 | 3.9, s | 56.8, q | 3.8, s | 56.8, q | 3.9, s | 56.8, q |
| 1′ | 161.7, s | 161.6, s | 42.7, t | |||
| 2′ | 117.7, s | 118.7, d | 3.4, br q | 14.1, q | ||
| 3′ | 7.9, br d | 123.2, d | 7.8, s | 157.1, s | 1.2, t(6.8) | 42.3, t |
| 4′ | 7.0, br t | 123.1, d | 119.1, d | 3.4, br q | 13.3, q | |
| 5′ | 7.1, br d | 118.4, d | 7.0, br d | 117.5, d | 1.3, t(6.8) | |
| 6′ | 146.6, s | 7.0, br d | 158.8, s | |||
| 7′ | 149.9, s | N | ||||
Measured in CDCl3 at 400 MHz for 1H and 100 MHz for 13C, respectively. J values in Hz.