Table 1. The mobilities (μ), threshold voltages (VTh), on/off ratios (Ion/Ioff), Ioff, and subthreshold slop (S) for as-prepared BGBC FET devices.
DPPTTT* | DPPTTT/NMe4I *† | ||||
7.5 | 15 | 30 | 45 | ||
μ‡ (cm2 V−1 s−1) | 0.8 (2.1) | 8.1 (12.9) | 15.4 (20.1) | 19.5 (26.2) | 13.6 (17.3) |
μ§ (cm2 V−1 s−1) | 0.6 (0.8) | 1.6 (2.2) | 2.8 (3.8) | 3.6 (4.4) | 2.4 (3.5) |
VTh (V) | −4 to 2 | −1 to 2 | −3 to 1 | −3 to 1 | −3 to 2 |
Ion/Ioff (log10) | 6–7 | 3–4 | 5–6 | 6–7 | 6–7 |
Ioff (A) (average) | 5.5 × 10−10 | 8.5 × 10−7 | 5.4 × 10−8 | 6.1 × 10−9 | 2.5 × 10−9 |
S (V decade−1) | 3–3.2 | 0.9–1.1 | 1.0–1.4 | 1.0–1.2 | 1.0–1.3 |
*All data were obtained in air based on more than 50 FET devices with W = 8800 μm and L = 80 μm at VDS = −60 V.
†Molar ratio of the repeat moiety of DPPTTT versus NMe4I.
‡Hole mobility, extracted by fitting the linear part of the plot of IDS1/2 versus VGS, in the form of average (high).
§Hole mobility, on the basis of two points of the plot of IDS1/2 versus VGS at VTh and VGS = −30 V using the equation IDS = Ciμ(VGS − VTh)2W/2L (see text), in the form of average (high).