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. 2016 Jul 1;11:321. doi: 10.1186/s11671-016-1529-z

Table 2.

Cycloaddition of CO2 with different epoxides catalyzed by DVB-HTA

Entry Epoxide Product Time (h) Con (%)a Sel (%)b
1 graphic file with name 11671_2016_1529_Figa_HTML.gif graphic file with name 11671_2016_1529_Figb_HTML.gif 3 90 98
2 graphic file with name 11671_2016_1529_Figc_HTML.gif graphic file with name 11671_2016_1529_Figd_HTML.gif 6 93 99
3 graphic file with name 11671_2016_1529_Fige_HTML.gif graphic file with name 11671_2016_1529_Figf_HTML.gif 6 89 98
4 graphic file with name 11671_2016_1529_Figg_HTML.gif graphic file with name 11671_2016_1529_Figh_HTML.gif 4 83 98
5 graphic file with name 11671_2016_1529_Figi_HTML.gif graphic file with name 11671_2016_1529_Figj_HTML.gif 12 56 63

Reaction conditions: epoxide (16 mmol), CO2 (1.2 MPa), catalyst DVB-HTA (0.05 g, 0.035 mmol), 120 °C

aThe yield for the cyclic carbonate product

bThe selectivity for the cyclic carbonate product, and the byproduct for entry 5 is mostly 1,2-hexanediol