Table 2.
Entry | Epoxide | Product | Time (h) | Con (%)a | Sel (%)b |
---|---|---|---|---|---|
1 | 3 | 90 | 98 | ||
2 | 6 | 93 | 99 | ||
3 | 6 | 89 | 98 | ||
4 | 4 | 83 | 98 | ||
5 | 12 | 56 | 63 |
Reaction conditions: epoxide (16 mmol), CO2 (1.2 MPa), catalyst DVB-HTA (0.05 g, 0.035 mmol), 120 °C
aThe yield for the cyclic carbonate product
bThe selectivity for the cyclic carbonate product, and the byproduct for entry 5 is mostly 1,2-hexanediol