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. 2016 Jun 27;198(14):1965–1973. doi: 10.1128/JB.00140-16

TABLE 2.

Observed properties of the TDM series molecules identified in this study

Name (abbreviation) Alternate name(s) Producing strain(s) Retention time (min) UV-Vis abs max (nm)a Mol formula Mol wt (g/mol) ESI-MS (m/z)b
Mass accuracy (ppm)
Observed Calculated
W4.9 WAC04657 4.9 260 C18H24O7 352 353.1598 353.1600 −0.6
Dihydro-tetrodecamycin (dhTDM) A5.4, G5.4 S atroolivaceus, S. globisporus 5.4 251 C18H24O6 336 337.1651 337.1651 0
W5.9 WAC04657 5.9 271 C18H24O6 336 337.1664 337.1651 3.9
W6.3 WAC04657 6.3 243 C18H22O5 318 341.1364 341.1365 −0.3
Tetrodecamycin (TDM) A6.4, G6.4, W6.4 WAC04657, S. atroolivaceus, S. globisporus 6.4 271 C18H22O6 334 335.1496 335.1495 0.3
13-Deoxy-tetrodecamycin (13-dTDM) W8.0 WAC04657 8.0 271 C18H22O5 318 319.1548 319.1545 0.9
a

UV-Vis absorbance maximum (abs max) was recorded on an HPLC column in a solution of 40% aqueous acetonitrile–0.1% formic acid.

b

ESI, electrospray ionization.