Table 2.
13C (150 MHz) NMR data of compounds 1–6 [δ in ppm, J in Hz]
No. | 1 | 2 | 3 | 4 | 5 | 6 |
---|---|---|---|---|---|---|
1 | 32.7 t | 32.5 t | 40.6 t | 33.7 t | 32.0 t | 153.5 d |
2 | 30.4 t | 30.3 t | 32.6 t | 37.8 t | 30.2 t | 127.2 d |
3 | 89.0 d | 88.7 d | 87.8 d | 215.3 s | 88.9 d | 204.3 s |
4 | 41.7 s | 41.3 s | 42.7 s | 50.4 s | 41.3 s | 46.6 s |
5 | 47.9 d | 47.3 d | 51.1 d | 48.4 d | 47.8 d | 47.2 d |
6 | 21.4 t | 21.1 t | 25.0 t | 21.4 t | 21.3 t | 25.7 t |
7 | 26.7 t | 26.3 t | 30.6 t | 26.1 t | 30.3 t | 20.3 t |
8 | 49.0 d | 47.6 d | 50.4 d | 46.1 d | 47.1 d | 45.7 d |
9 | 20.3 s | 20.5 s | 140.3 s | 21.9 s | 20.2 s | 25.8 s |
10 | 26.9 s | 27.0 s | 138.7 s | 26.6 s | 27.4 s | 30.6 s |
11 | 26.7 t | 37.8 t | 135.9 d | 41.0 t | 26.7 t | 46.1 t |
12 | 34.4 t | 77.6 d | 46.7 s | 72.6 d | 30.3 t | 210.8 s |
13 | 42.2 s | 46.3 s | 46.7 s | 51.5 s | 47.5 s | 47.5 s |
14 | 47.6 s | 48.6 s | 49.8 s | 48.2 s | 49.9 s | 60.8 s |
15 | 80.6 d | 79.6 d | 79.2 d | 44.0 t | 79.3 d | 46.1 t |
16 | 112.3 s | 112.6 s | 112.7 s | 72.8 d | 151.3 s | 73.0 d |
17 | 59.9 d | 59.9 d | 58.7 d | 53.3 d | 121.7 s | 48.7 d |
18 | 19.0 q | 13.1 q | 11.9 q | 13.7 q | 24.6 q | 14.6 q |
19 | 31.2 t | 31.2 t | 129.6 d | 29.6 t | 32.4 t | 32.6 t |
20 | 24.4 d | 24.3 d | 24.0 d | 35.1 d | 27.9 d | 25.7 d |
21 | 19.9 q | 20.1 q | 21.2 q | 18.8 q | 20.7 q | 21.8 q |
22 | 38.5 t | 38.8 t | 38.9 t | 87.9 d | 37.2 t | 41.3 t |
23 | 72.2 d | 74.9 d | 72.4 d | 106.0 s | 77.0 d | 106.9 s |
24 | 90.5 d | 86.9 d | 90.6 d | 83.8 d | 80.2 d | 86.3 d |
25 | 71.3 s | 146.1 s | 71.4 s | 83.9 s | 72.3 s | 78.2 s |
26 | 24.3 q | 113.5 t | 27.6 q | 25.3 q | 27.1 q | 78.9 t |
27 | 25.7 q | 18.5 q | 26.0 q | 28.3 q | 28.5 q | 23.6 q |
28 | 12.2 q | 12.4 q | 10.4 q | 21.1 q | 15.6 q | 20.3 q |
29 | 26.0 q | 25.7 q | 25.0 q | 22.9 q | 25.7 q | 22.2 q |
30 | 15.7 q | 15.5 q | 15.4 q | 20.1 q | 14.6 q | 19.6 q |
AcO-12 | 21.6 q | |||||
170.9 s | ||||||
AcO-24 | 21.3 q | |||||
171.4 s | ||||||
Sugar | ||||||
1′ | 107.7 d | 105.0 d | 108.0 d | 105.0 d | ||
2′ | 76.1 d | 76.0 d | 76.1 d | 76.0 d | ||
3′ | 75.3 d | 76.6 d | 79.2 d | 76.6 d | ||
4′ | 73.5 d | 71.9 d | 71.7 d | 71.7 d | ||
5′ | 63.5 t | 67.4 t | 67.7 t | 67.5 t | ||
AcO-2′ | 170.4 1 | 170.4 s | ||||
22.0 | 21.6 q | |||||
AcO-4′ | 21.2 q | |||||
171.0 s |