Table 2.
EPR parameters obtained from the simulation of cw EPR spectra of the SL1-A β samples
| Fast | Medium | Slow | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| D/P | τ r a | Azz | lw | %b | τ r | Azz | lw | % | τ r | Azz | lw | %c |
| (ns) | (MHz) | (MHz) | (ns) | (MHz) | (MHz) | (ns) | (MHz) | (MHz) | ||||
| 0 | 0.19 | 110 | 0.14 | 10 | 2.55 ± 0.35 | 110 | 0.32 | 51 | > 50 | 95 | 0.50 | 39 |
| 2.7 | 0.43 | 110 | 0.14 | 2.5 | 4.80 ± 0.40 | 110 | 0.32 | 64 | > 50 | 95 | 0.50 | 33.5 |
| 5.4 | 0.43 | 110 | 0.14 | 2.5 | 4.65 ± 0.55 | 110 | 0.32 | 75 | > 50 | 95 | 0.50 | 22.5 |
| 7.3 | 0.19 | 110 | 0.14 | 10 | 1.76 ± 0.16 | 110 | 0.14 | 90 | – | – | – | – |
| 12.7 | 0.19 | 110 | 0.14 | 7 | 1.55 ± 0.08 | 110 | 0.14 | 92 | – | – | – | – |
| 65.4 | – | – | – | – | 0.93 ± 0.03 | 110 | 0.06 | 100 | – | – | – | – |
| 130.9 | – | – | – | – | 0.93 ± 0.03 | 110 | 0.06 | 100 | – | – | – | – |
Given are: τ r, rotation-correlation time, Azz, the hyperfine splitting along the z-direction, lw, the component line width of the simulation and % stands for the contribution of the component to the total spectrum
a Errors: ± 0.02 ns
b Errors: ± 1%
c Errors: ± 4.00%