Table 2. Overview of photoswitch characteristics.
Entry | Switch | t1/2 | λmax (nm) |
PSS for irradiation at
λ** |
|||
---|---|---|---|---|---|---|---|
365 | 430 | 590 | White light | ||||
1 | Azo 3 | >8 h | 360 (π–π*) | 4:96 | 70:30 | ND | 77:23 |
445 (n–π*) | |||||||
2 | Azo 4 | 180 s | 434 (π–π*) | ND | ND | ND | ND |
374 (n–π*) | |||||||
3 | Azo 5 | >8 h | 320 (π–π*) | 32:68† | 82:18 | ND | 77:23 |
436 (n–π*) | |||||||
4 | Azo 6 | >8 h | 348 (π–π*) | <3:97 | 69:31 | ND | 76:24 |
444 (n–π*) | |||||||
5 | DASA 1 | 37 s | 570 | ND | ND | <20:80‡ | <20:80‡ |
6 | DASA 2 | 130 s | 545 | ND | ND | <20:80‡,§ | <20:80‡ |
DASA, donor–acceptor Stenhouse adduct; ND, not determined; PSS, photostationary state.
**Trans/cis
†Same for 312 nm.
‡Open/cyclized.
§546 nm.