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. 2016 Feb 26;55(16):4882–4907. doi: 10.1002/anie.201508928

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© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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Structural formulas (left) of DNCCs 8 a/8 b (from barley)57 and ent ‐8 a (from a Norway maple leaf),58 whose CD and UV spectra (right) feature the properties of an intriguing enantiomer of 8 a.