Table 6. Residual levels of PA cyclic monomers and oligomers in PA kitchen utensils.
Articles | Material type | PA6 cyclic monomer and oligomers | PA66 cyclic monomer and oligomers | Total | PA6:PA66 | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Monomer | Dimer | Trimer | Tetramer | Pentamer | Hexamer | Subtotal | Monomer | Dimer | Trimer | Subtotal | ||||
Ladle 1 | 6 | 4.8 | 2.8 | 2.8 | 4.6 | 2.8 | 1.4 | 19 | 0.11 | 0.088 | 0.063 | 0.26 | 19 | 99:1 |
Sesame grinder | 6 | 3.7 | 0.8 | 1.6 | 5.0 | 2.8 | 1.3 | 15 | ND | ND | ND | ND | 15 | 100:0 |
Turner 1 | 66 | 0.026 | 0.013 | 0.019 | 0.040 | 0.011 | 0.008 | 0.11 | 5.4 | 5.3 | 3.2 | 14 | 14 | 1:99 |
Turner 2 | 66 | 0.003 | ND | ND | ND | ND | ND | 0.003 | 4.7 | 4.5 | 3.9 | 13 | 13 | 0:100* |
Turner 3 | 66 | ND | ND | ND | ND | ND | ND | ND | 4.4 | 4.4 | 3.7 | 13 | 13 | 0:100* |
Turner 4 | 66 | 0.056 | 0.002 | ND | ND | ND | ND | 0.057 | 4.8 | 4.9 | 3.9 | 14 | 14 | 0:100* |
Turner 5 | 66 | 0.086 | 0.006 | 0.033 | 0.060 | 0.016 | 0.021 | 0.22 | 3.0 | 3.0 | 2.9 | 8.9 | 9.1 | 2:98 |
Turner 6 | 66 | 0.004 | ND | ND | ND | ND | ND | 0.004 | 2.8 | 3.2 | 3.2 | 9.1 | 9.1 | 0:100* |
Turner 7 | 66 | 0.025 | 0.005 | 0.012 | 0.029 | 0.010 | 0.009 | 0.091 | 4.7 | 4.8 | 4.2 | 14 | 14 | 1:99 |
Turner 8 | 66 | 0.062 | 0.025 | 0.041 | 0.088 | 0.026 | 0.024 | 0.27 | 6.7 | 6.7 | 6.2 | 20 | 20 | 1:99 |
Turner 9 | 66 | ND | ND | ND | ND | ND | ND | ND | 5.2 | 5.3 | 3.4 | 14 | 14 | 0:100* |
Ladle 2 | 66 | ND | ND | ND | ND | ND | ND | ND | 5.3 | 5.5 | 4.3 | 15 | 15 | 0:100* |
Ladle 3 | 66 | 0.029 | 0.005 | 0.015 | 0.030 | 0.011 | 0.007 | 0.096 | 2.7 | 2.6 | 2.4 | 7.7 | 7.8 | 1:99 |
Ladle 4 | 66 | 0.011 | ND | ND | ND | ND | ND | 0.011 | 3.5 | 3.4 | 1.9 | 8.9 | 8.9 | 1:99 |
Ladle 6 | 66 | 0.12 | 0.010 | 0.025 | 0.050 | 0.018 | 0.016 | 0.24 | 3.6 | 4.4 | 4.2 | 12 | 12 | 2:98 |
Ladle 7 | 66 | 0.023 | 0.005 | 0.011 | 0.027 | 0.009 | 0.009 | 0.083 | 5.2 | 5.3 | 4.6 | 15 | 15 | 1:99 |
Ladle 8 | 66 | 0.033 | 0.006 | 0.013 | 0.031 | 0.010 | 0.009 | 0.10 | 2.8 | 2.8 | 2.3 | 7.9 | 8.0 | 1:99 |
Ladle 9 | 66 | 0.059 | ND | ND | ND | ND | ND | 0.059 | 6.0 | 5.9 | 4.6 | 16 | 17 | 0:100* |
Ladle 10 | 66 | 0.064 | ND | ND | ND | ND | ND | 0.064 | 4.7 | 4.3 | 3.4 | 12 | 12 | 1:99 |
Ladle 5 | 6/66 | 1.2 | 0.51 | 0.60 | 1.3 | 0.87 | 0.58 | 5.0 | 1.6 | 2.1 | 2.4 | 6.1 | 11 | 45:55 |
Turner 10 | 6/66 | 0.63 | 0.43 | 0.27 | 0.80 | 0.48 | 0.23 | 2.8 | 3.5 | 3.7 | 3.2 | 10 | 13 | 22:78 |
Cake server | 6/66 | 1.6 | 0.32 | 0.52 | 1.4 | 0.82 | 0.45 | 5.1 | 3.7 | 3.9 | 3.8 | 11 | 17 | 31:69 |
Cake scraper | 6/66 | 0.74 | 0.11 | 0.28 | 0.58 | 0.23 | 0.10 | 2.1 | 4.2 | 4.1 | 3.7 | 12 | 14 | 15:85 |
Each value (mg/g) is the mean of two trials.
ND: < 0.002 mg/g
*0:100: PA6 ratios below 0.4.