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. 2016 Jul 25;11(7):e0159547. doi: 10.1371/journal.pone.0159547

Table 6. Residual levels of PA cyclic monomers and oligomers in PA kitchen utensils.

Articles Material type PA6 cyclic monomer and oligomers PA66 cyclic monomer and oligomers Total PA6:PA66
Monomer Dimer Trimer Tetramer Pentamer Hexamer Subtotal Monomer Dimer Trimer Subtotal
Ladle 1 6 4.8 2.8 2.8 4.6 2.8 1.4 19 0.11 0.088 0.063 0.26 19 99:1
Sesame grinder 6 3.7 0.8 1.6 5.0 2.8 1.3 15 ND ND ND ND 15 100:0
Turner 1 66 0.026 0.013 0.019 0.040 0.011 0.008 0.11 5.4 5.3 3.2 14 14 1:99
Turner 2 66 0.003 ND ND ND ND ND 0.003 4.7 4.5 3.9 13 13 0:100*
Turner 3 66 ND ND ND ND ND ND ND 4.4 4.4 3.7 13 13 0:100*
Turner 4 66 0.056 0.002 ND ND ND ND 0.057 4.8 4.9 3.9 14 14 0:100*
Turner 5 66 0.086 0.006 0.033 0.060 0.016 0.021 0.22 3.0 3.0 2.9 8.9 9.1 2:98
Turner 6 66 0.004 ND ND ND ND ND 0.004 2.8 3.2 3.2 9.1 9.1 0:100*
Turner 7 66 0.025 0.005 0.012 0.029 0.010 0.009 0.091 4.7 4.8 4.2 14 14 1:99
Turner 8 66 0.062 0.025 0.041 0.088 0.026 0.024 0.27 6.7 6.7 6.2 20 20 1:99
Turner 9 66 ND ND ND ND ND ND ND 5.2 5.3 3.4 14 14 0:100*
Ladle 2 66 ND ND ND ND ND ND ND 5.3 5.5 4.3 15 15 0:100*
Ladle 3 66 0.029 0.005 0.015 0.030 0.011 0.007 0.096 2.7 2.6 2.4 7.7 7.8 1:99
Ladle 4 66 0.011 ND ND ND ND ND 0.011 3.5 3.4 1.9 8.9 8.9 1:99
Ladle 6 66 0.12 0.010 0.025 0.050 0.018 0.016 0.24 3.6 4.4 4.2 12 12 2:98
Ladle 7 66 0.023 0.005 0.011 0.027 0.009 0.009 0.083 5.2 5.3 4.6 15 15 1:99
Ladle 8 66 0.033 0.006 0.013 0.031 0.010 0.009 0.10 2.8 2.8 2.3 7.9 8.0 1:99
Ladle 9 66 0.059 ND ND ND ND ND 0.059 6.0 5.9 4.6 16 17 0:100*
Ladle 10 66 0.064 ND ND ND ND ND 0.064 4.7 4.3 3.4 12 12 1:99
Ladle 5 6/66 1.2 0.51 0.60 1.3 0.87 0.58 5.0 1.6 2.1 2.4 6.1 11 45:55
Turner 10 6/66 0.63 0.43 0.27 0.80 0.48 0.23 2.8 3.5 3.7 3.2 10 13 22:78
Cake server 6/66 1.6 0.32 0.52 1.4 0.82 0.45 5.1 3.7 3.9 3.8 11 17 31:69
Cake scraper 6/66 0.74 0.11 0.28 0.58 0.23 0.10 2.1 4.2 4.1 3.7 12 14 15:85

Each value (mg/g) is the mean of two trials.

ND: < 0.002 mg/g

*0:100: PA6 ratios below 0.4.