Table S2.

Total Dexter coupling and BE and DAE contributions of seven-bond folded alkanes (Fig. 2B) with lowered average energy gaps compared with the values for Table S1 (main text)

Conformation	$V_{\text{tr}},$ eV	$V_{\text{tr}}^{\left(\text{be}\right)},$ eV	$V_{\text{tr}}^{\left(\text{dae}\right)},$ eV
Conf1	$2.14\times {10}^{-4}$	$2.17\times {10}^{-4}$	$1.33\times {10}^{-6}$
Conf2	$4.67\times {10}^{-5}$	$4.68\times {10}^{-5}$	$1.58\times {10}^{-7}$
Conf3	$2.34\times {10}^{-5}$	$4.26\times {10}^{-5}$	$1.58\times {10}^{-5}$
Conf4	$2.68\times {10}^{-4}$	$2.43\times {10}^{-4}$	$2.46\times {10}^{-5}$
Conf5	$1.60\times {10}^{-4}$	$1.12\times {10}^{-4}$	$3.41\times {10}^{-5}$