Table 3.
Statistics of library search results of Fit, RevFit and Purity for stilbenes obtained in twenty standard solutions with a concentration of DES, DIE and HEX corresponding to 0.1–1 μg L−1 in the urine sample and in urine samples spiked at 1 μg L−1
| Analyte | Fit index | Standard | Matrix | Meanstandard − Meanmatrix (%) | CVstandard − CVmatrix | ||
|---|---|---|---|---|---|---|---|
| Mean | CV (%) | Mean | CV (%) | ||||
| DES | Fit | 0.89 | 8.0 | 0.94 | 4.0 | −5.68 | 3.9 |
| RevFit | 0.94 | 5.0 | 0.87 | 7.7 | 6.63 | −2.7 | |
| Purity | 0.85 | 7.4 | 0.84 | 8.5 | 0.93 | −1.0 | |
| DIE | Fit | 0.97 | 3.5 | 0.98 | 1.7 | −0.77 | 1.8 |
| RevFit | 0.98 | 2.3 | 0.96 | 4.0 | 2.30 | −1.7 | |
| Purity | 0.96 | 4.4 | 0.95 | 4.3 | 0.78 | 0.0 | |
| HEX | Fit | 0.86 | 7.3 | 0.91 | 3.5 | −6.33 | 3.8 |
| RevFit | 0.91 | 5.3 | 0.86 | 9.2 | 4.88 | −3.9 | |
| Purity | 0.83 | 7.4 | 0.82 | 7.5 | 0.70 | −0.1 | |