Table 2.

Ir-catalyzed allylations of acyclic α-alkoxy ketone enolates: scope of allylic carbonates.^[a]

^[a]The molar ratio of 1a/2/3/LHMDS/CuBr = 2/1/0.02/2/2. The absolute configurations were assigned by analogy. The structure of 4ag was determined by X-ray analysis. The yields were reported as the combined yields of two diastereoisomers. The diastereomeric ratios were determined by ¹H NMR analysis of crude reaction mixtures. The enantiomeric excesses were determined by chiral SFC analysis of major isomers.

^[b]0.5 equiv. of CuBr was used.