Table 2.

Glycoforms detected in rice plastidial NPP1

Peak no.a	m/zb	Δc	Estimated composition	Relative contents (%)d
1	688.9915	−0.268	HexNAc2 Pent2	0.108 ± 0.033
4	749.0722	−0.209	Hex2 HexNAc2	0.132 ± 0.056
5	780.0588	−0.217	Hex1 HexNAc1 Pent3	0.007 ± 0.005
6	851.0808	−0.232	Hex1 HexNAc2 Pent2	0.037 ± 0.003
9	895.1576	−0.181	Hex2 HexNAc2 dHex1	0.006 ± 0.001
10	911.149	−0.185	Hex3 HexNAc2	0.359 ± 0.075
12	1,027.204	−0.178	Hex2 HexNAc2 dHex1 Pent1	0.338 ± 0.143
13	1,032.178	−0.182	Hex5 HexNAc1	0.088 ± 0.034
14	1,043.203	−0.174	Hex3 HexNAc2 Pent1	3.144 ± 0.109
15	1,057.220	−0.171	Hex3 HexNAc2 dHex1	0.249 ± 0.139
16	1,073.216	−0.171	Hex4 HexNAc2	0.137 ± 0.013
18	1,114.242	−0.172	Hex3HexNAc3	0.061 ± 0.000
19	1,175.243	−0.176	Hex3 HexNAc2 Pent2	0.011 ± 0.006
20	1,189.274	−0.160	Hex3 HexNAc2 dHex1 Pent1	23.146 ± 1.786
22	1,203.290	−0.159	Hex3 HexNAc2 dHex2	0.464 ± 0.215
23	1,205.274	−0.155	Hex4 HexNAc2 Pent1	0.406 ± 0.245
24	1,219.304	−0.141	Hex4 HexNAc2 dHex1	0.010 ± 0.006
27	1,235.288	−0.152	Hex5 HexNAc2	2.519 ± 0.135
28	1,246.306	−0.150	Hex3 HexNAc3 Pent1	3.321 ± 0.305
29	1,260.319	−0.153	Hex3 HexNAc3 dHex1	0.148 ± 0.059
30	1,276.311	−0.155	Hex4 HexNAc3	0.063 ± 0.026
31	1,351.343	−0.144	Hex4 HexNAc2 dHex1 Pent1	0.828 ± 0.011
33	1,367.343	−0.138	Hex5 HexNAc2 Pent1	0.161 ± 0.009
34	1,381.356	−0.142	Hex5 HexNAc2 dHex1	0.030 ± 0.007
35	1,392.371	−0.143	Hex3 HexNAc3 dHex1 Pent1	10.904 ± 0.531
36	1,397.347	−0.146	Hex6 HexNAc2	8.345 ± 0.129
37	1,406.389	−0.140	Hex3 HexNAc3 dHex2	0.331 ± 0.043
38	1,408.377	−0.132	Hex4 HexNAc3 Pent1	1.611 ± 0.218
39	1,422.396	−0.128	Hex4 HexNAc3 dHex1	0.138 ± 0.046
40	1,438.388	−0.131	Hex5 HexNAc3	0.151 ± 0.013
41	1,449.402	−0.133	Hex3 HexNAc4 Pent1	5.496 ± 0.372
42	1,463.431	−0.120	Hex3 HexNAc4 dHex1	0.222 ± 0.018
43	1,513.414	−0.125	Hex5 HexNAc2 dHex1 Pent1	0.143 ± 0.044
45	1,554.439	−0.127	Hex4 HexNAc3 dHex1 Pent1	3.191 ± 0.327
46	1,559.417	−0.128	Hex7 HexNAc2	5.511 ± 1.141
47	1,568.455	−0.126	Hex4 HexNAc3 dHex2	0.108 ± 0.002
48	1,570.446	−0.116	Hex5 HexNAc3 Pent1	0.415 ± 0.005
49	1,581.453	−0.125	Hex3 HexNAc4 Pent2	0.036 ± 0.014
50	1,584.458	−0.119	Hex5 HexNAc3 dHex1	0.059 ± 0.001
51	1,595.470	−0.122	Hex3 HexNAc4 dHex1 Pent1	11.533 ± 0.292
52	1,609.496	−0.113	Hex3 HexNAc4 dHex2	2.017 ± 2.223
53	1,611.481	−0.107	Hex4 HexNAc4 Pent1	0.651 ± 0.087
54	1,625.495	−0.109	Hex4 HexNAc4 dHex1	0.106 ± 0.000
56	1,656.547	−0.051	Hex3 HexNAc3 dHex1 Pent3	0.004 ± 0.000
57	1,666.579	−0.051	Hex3 HexNAc5 dHex1	0.005 ± 0.005
58	1,700.517	−0.107	Hex4 HexNAc3 dHex2 Pent1	0.229 ± 0.059
59	1,716.518	−0.101	Hex5 HexNAc3 dHex1 Pent1	0.458 ± 0.335
60	1,721.490	−0.108	Hex8 HexNAc2	5.471 ± 0.583
61	1,730.529	−0.105	Hex5 HexNAc3 dHex2	0.045 ± 0.007
62	1,732.518	−0.096	Hex6 HexNAc3 Pent1	0.025 ± 0.015
63	1,757.543	−0.103	Hex4 HexNAc4 dHex1 Pent1	2.282 ± 1.720
64	1,771.565	−0.096	Hex4 HexNAc4 dHex2	0.151 ± 0.042
66	1,787.561	−0.096	Hex5 HexNAc4 dHex1	0.025 ± 0.001
68	1,846.610	−0.072	Hex4 HexNAc3 dHex3 Pent1	0.002 ± 0.001
69	1,862.593	−0.084	Hex5 HexNAc3 dHex2 Pent1	0.054 ± 0.005
70	1,878.6	−0.072	Hex6 HexNAc3 dHex1 Pent1	0.031 ± 0.024
71	1,883.565	−0.086	Hex9 HexNAc2	1.370 ± 0.428
72	1,903.616	−0.088	Hex4 HexNAc4 dHex2 Pent1	1.738 ± 0.086
73	1,919.620	−0.079	Hex5 HexNAc4 dHex1 Pent1	0.815 ± 0.035
74	1,933.639	−0.075	Hex5 HexNAc4 dHex2	0.038 ± 0.005
78	1,962.665	−0.065	Hex3 HexNAc3 dHex4 Pent2	0.008 ± 0.004
79	1,964.611	−0.098	Hex4 HexNAc3 dHex2 Pent3	0.012 ± 0.002
80	2,045.653	−0.050	Hex10 HexNAc2	0.005 ± 0.001
81	2,065.692	−0.064	Hex5 HexNAc4 dHex2 Pent1	0.045 ± 0.012
82	2,079.713	−0.059	Hex5 HexNAc4 dHex3	0.025 ± 0.000
83	2,081.756	0.003	Hex6 HexNAc4 dHex1 Pent1	2.282 ± 0.006
85	2,211.765	−0.050	Hex5 HexNAc4 dHex3 Pent1	0.151 ± 0.027

Compositional annotations for the peaks detected in MALDI-TOF MS were achieved using KEGG Glycan and GlycoSuite online databases.

Hex, hexose; HexNAc, N-acetylhexosamine; dHex, deoxyhexose; Pent, pentose.

^aPeak number indicated in Fig. 5.

^bMass-to-charge ratio.

^cDifference from the theoretical mass value.

^dValues show the averages of duplicate experiments.