Table 5.

Glycoforms detected in rice NPP6

Peak no.a	m/zb	Δc	Estimated composition	Relative contents (%)d
8	880.7558	−0.568	Hex2 HexNAc2 Pent1	0.00 ± 0.00e
9	894.7836	−0.555	Hex2 HexNAc2 dHex1	0.00 ± 0.00e
10	910.753	−0.581	Hex3 HexNAc2	0.00 ± 0.00e
12	1,026.8222	−0.560	Hex2 HexNAc2 dHex1 Pent1	0.02 ± 0.00
14	1,042.805	−0.572	Hex3 HexNAc2 Pent1	1.05 ± 0.16
15	1,056.806	−0.586	Hex3 HexNAc2 dHex1	0.00 ± 0.00e
16	1,072.7896	−0.601	Hex4 HexNAc2	0.02 ± 0.01
20	1,188.8735	−0.560	Hex3 HexNAc2 dHex1 Pent1	11.66 ± 0.75
23	1,204.8407	−0.588	Hex4 HexNAc2 Pent1	0.43 ± 0.02
26	1,230.8615	0.397	Hex2 HexNAc3 Pent1 dHex1	0.04 ± 0.01
27	1,234.8493	−0.590	Hex5 HexNAc2	1.16 ± 0.19
28	1,244.9241	−1.532	Hex3 HexNAc3 Pent1	1.30 ± 0.22
29	1,261.8621	1.389	Hex3 HexNAc3 dHex1	0.01 ± 0.00
31	1,350.8699	−0.617	Hex4 HexNAc2 dHex1 Pent1	0.24 ± 0.04
33	1,366.8419	−0.640	Hex5 HexNAc2 Pent1	0.03 ± 0.01
35	1,391.9241	−0.590	Hex3 HexNAc3 dHex1 Pent1	9.42 ± 0.32
36	1,396.8932	−0.600	Hex6 HexNAc2	11.85 ± 0.72
38	1,407.9079	−0.601	Hex4 HexNAc3 Pent1	1.35 ± 0.17
40	1,438.9019	0.382	Hex5 HexNAc3	0.10 ± 0.02
41	1,447.9816	−1.553	Hex3 HexNAc4 Pent1	0.82 ± 0.17
43	1,512.9161	−0.624	Hex5 HexNAc2 dHex1 Pent1	0.01 ± 0.00
45	1,553.9508	−0.616	Hex4 HexNAc3 dHex1 Pent1	2.42 ± 0.12
46	1,558.9192	−0.626	Hex7 HexNAc2	5.12 ± 0.42
48	1,569.939	−0.623	Hex5 HexNAc3 Pent1	0.19 ± 0.05
51	1,594.9819	−0.611	Hex3 HexNAc4 dHex1 Pent1	27.45 ± 1.32
53	1,610.0227	−1.569	Hex4 HexNAc4 Pent1	1.13 ± 0.06
55	1,651.0562	−1.559	Hex3 HexNAc5 Pent1	0.00 ± 0.00e
58	1,699.9968	−0.628	Hex4 HexNAc3 dHex2 Pent1	1.10 ± 0.10
59	1,715.9949	−0.624	Hex5 HexNAc3 dHex1 Pent1	0.27 ± 0.05
60	1,720.9711	−0.627	Hex8 HexNAc2	1.91 ± 0.23
63	1,757.0222	−0.624	Hex4 HexNAc4 dHex1 Pent1	3.41 ± 0.21
65	1,773.0269	−0.614	Hex5 HexNAc4 Pent1	0.08 ± 0.02
67	1,813.0896	0.401	Hex3 HexNAc3 dHex2	0.00 ± 0.00e
69	1,862.0539	−0.623	Hex5 HexNAc3 dHex2 Pent1	0.05 ± 0.01
71	1,883.0133	−0.638	Hex9 HexNAc2	0.15 ± 0.05
72	1,903.0693	−0.635	Hex4 HexNAc4 dHex2 Pent1	12.48 ± 0.67
73	1,919.0714	−0.627	Hex5 HexNAc4 dHex1 Pent1	0.83 ± 0.10
75	1,935.1201	−0.574	Hex6 HexNAc4 Pent1	0.02 ± 0.02
76	1,945.1061	0.374	Hex3 HexNAc5 dHex2 Pent1	0.10 ± 0.03
77	1,959.1654	0.419	Hex3 HexNAc5 dHex3	0.00 ± 0.00e
81	2,065.1188	−0.638	Hex5 HexNAc4 dHex2 Pent1	1.26 ± 0.19
85	2,211.1646	−0.650	Hex5 HexNAc4 dHex3 Pent1	2.54 ± 0.30

Compositional annotations for the peaks detected in MALDI-TOF MS were achieved using KEGG Glycan and GlycoSuite online databases.

Hex, hexose; HexNAc, N-acetylhexosamine; dHex, deoxyhexose; Pent, pentose.

^aPeak number indicated in Fig. 5.

^bMass-to-charge ratio.

^cDifference from the theoretical mass value.

^dValues are represented as mean ± SD (n = 3).

^eGlycan peaks are detected in this analysis.