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. Author manuscript; available in PMC: 2017 May 23.
Published in final edited form as: Chemistry. 2016 Apr 28;22(22):7399–7402. doi: 10.1002/chem.201601320

Table 3.

Improved Coupling of Aryl and Alkyl Halides[a].

graphic file with name nihms805981t3.jpg

Entry bpyNiI2 [mol %] Time Yield 6 [%][b]
1 1.0 18 h 85
2 2.5 14 h 78
3 5.0 3 h 78
4 10.0 60 min 84
5[c] 10.0 20 min 79
[a]

Reactions performed on 0.5 mmol scale using a 1:1 ratio of starting materials.

[b]

Determined by GC using dodecane as an internal standard.

[c]

60 °C.