Table 4.
compound | solvent |
|
εmax(M−1 cm−1)b | λex (nm)c |
|
RQYe | SS (cm−1)f | ||
---|---|---|---|---|---|---|---|---|---|
external BN indole | cyclohexane | 281.5 | 5 809 | 285 | 300 | 1.000 | 18.5 | ||
diethyl ether | 283.0 | 7 928 | 285 | 303 | 0.316 | 20.0 | |||
dichloromethane | 282.5 | 13 656 | 285 | 303 | 0.035 | 20.5 | |||
chloroform | 281.5 | 8 586 | 285 | 299 | 0.001 | 17.5 | |||
acetonitrile | 283.0 | 20 348 | 285 | 304 | 0.482 | 21.0 | |||
dimethyl sulfoxide | 286.0 | 3 698 | 285 | 309 | 0.116 | 23.0 | |||
fused BN indole | cyclohexane | 295.0 | 13 105 | 295 | 341 | 1.000 | 46.0 | ||
diethyl ether | 298.5 | 58 080 | 303 | 358 | 0.680 | 59.5 | |||
dichloromethane | 296.0 | 21 810 | 295 | 363 | 0.582 | 67.0 | |||
chloroform | 290.5 | 50 300 | 295 | 367 | 0.005 | 76.5 | |||
acetonitrile | 297.5 | 42 008 | 295 | 370 | 0.686 | 72.5 | |||
dimethyl sulfoxide | 305.0 | 14 807 | 295 | 378 | 0.688 | 73.0 |
Absorption maximum wavelength.
Extinction coefficient at absorption maximum.
Excitation wavelength for detection of fluorescence spectra.
Fluorescence spectrum maximum wavelength.
Relative quantum yield.
Stokes’ shift.