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. Author manuscript; available in PMC: 2016 Aug 6.
Published in final edited form as: J Phys Chem B. 2015 Jun 3;119(25):7985–7993. doi: 10.1021/acs.jpcb.5b03485

Table 4.

Solvent Dependent Absorption and Fluorescence Spectra

compound solvent
λabmax(nm)
a
εmax(M−1 cm−1)b λex (nm)c
λFmax(nm)
d
RQYe SS (cm−1)f
external BN indole cyclohexane 281.5 5 809 285 300 1.000 18.5
diethyl ether 283.0 7 928 285 303 0.316 20.0
dichloromethane 282.5 13 656 285 303 0.035 20.5
chloroform 281.5 8 586 285 299 0.001 17.5
acetonitrile 283.0 20 348 285 304 0.482 21.0
dimethyl sulfoxide 286.0 3 698 285 309 0.116 23.0
fused BN indole cyclohexane 295.0 13 105 295 341 1.000 46.0
diethyl ether 298.5 58 080 303 358 0.680 59.5
dichloromethane 296.0 21 810 295 363 0.582 67.0
chloroform 290.5 50 300 295 367 0.005 76.5
acetonitrile 297.5 42 008 295 370 0.686 72.5
dimethyl sulfoxide 305.0 14 807 295 378 0.688 73.0
a

Absorption maximum wavelength.

b

Extinction coefficient at absorption maximum.

c

Excitation wavelength for detection of fluorescence spectra.

d

Fluorescence spectrum maximum wavelength.

e

Relative quantum yield.

f

Stokes’ shift.