Table 3. MALDI TOF/TOF fragmentation of C201-containing tryptic peptide NKTEVDIYNSDPLICR (187–202).
Observed [M+H]+ | Modification | y-5 Fragment | Observed m/z fragment | Calculated m/z fragment | Error (ppm) |
---|---|---|---|---|---|
1879.7920 | None | PLICR | 601.3415 | 601.3490 | −12.5 |
1936.8920 | CAM | PLICR | 658.3679 | 658.3705 | −3.95 |
2017.9983 | DMD | PLICR | 739.4206 | 739.4170 | 4.87 |
Related MS/MS spectra are reported in the Supplementary Information (Fig. S2).