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Lanthionine bond formation. A) Nisin and its precursor peptide. B) Mechanism of lanthionine bond formation for class I–IV lanthionine synthetases. GTP is used in an analogous way to ATP by some enzymes, for example in the biosynthesis of labyrinthopeptin A2. C) Labyrinthopeptin A2 and its precursor peptide. D) Mechanism for labionin formation in the biosynthesis of labyrinthopeptin A2.
