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Fragmentation of hydroperoxy acetals 178a–e catalyzed by Ca(OCl)2 or t-BuOCl.
 | |||||||
| Substrate | Product | Ca(OCl)2 (equiv) | Time (min) | Yield, % | t-BuOCl (equiv) | Time (min) | Yield, % |
| 178a | 179a | 1.3 | 10 | 75 | 0.25 | 15 | 78 |
| 178b | 179b | 1.3 | 10 | 86 | 1.2 | 10 | 85 |
| 178c | 179c | 1.3 | 10 | 83 | 1.2 | 10 | 84 |
| 178d | 179d | 1.3 | 10 | 85 | 0.25 | 15 | 85 |
| 178e | 179e | 1.3 | 10 | 82 | 1.2 | 10 | 84 |
