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. 2016 Aug 3;12:1647–1748. doi: 10.3762/bjoc.12.162

Table 15.

DBU-catalyzed isomerization−dehydration of saturated fulvene endoperoxides 275 to form 2-vinyl-2-cyclopentenones 277.

graphic file with name Beilstein_J_Org_Chem-12-1647-i066.jpg

Endoperoxide Cyclopentenone Yield, %

Inline graphic
275a
Inline graphic
277a
76
Inline graphic
275b
Inline graphic
277b
83
Inline graphic
275c
Inline graphic
277c
82
Inline graphic
275d
Inline graphic
277d
68