Table 19.
Examples of the Smith rearrangement.
| Entry | Allylic isomer B | Allylic isomer C | Comments | Ref. |
| 1 |
 429a |
 429b |
In CDCl3 within 259 h, approximately 5% of B was transformed into C | [427] |
| 2 |
 430a |
 430b |
In CHCl3 at room temperature within 150 h, the B:C ratio reached 1.8:1 | [439] |
| 3 |
 431a |
 431b |
In CDCl3 at 40 °C within 3.5 h, B is transformed into C by 20%. In EtOAc at 40 °C, the yield of C was 25–30% | [416] |
| In CHCl3 after 5 d at room temperature, only partial conversion | [431] | |||
| 4 |
 432a |
 432b |
In CDCl3, the B:C ratio reached 1:1.5 | [439] |