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. 2016 Aug 3;12:1647–1748. doi: 10.3762/bjoc.12.162

Table 25.

Products of thermal decomposition and photolysis of endoperoxides 261g, 263, 512a-c.

Endoperoxide Diepoxide, 513 Keto epoxides, 514 Ratio of products, 513:514
Inline graphic
261g 		Inline graphic
a 		Inline graphic
a 		Δ 36:65
hν 28:72
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263 		Inline graphic
b 		Inline graphic
b 		Δ 90:10
hν 33:67
Inline graphic
512a 		Inline graphic
c 		Inline graphic
c 		Δ –
hν 35:65
Inline graphic
512b 		Inline graphic
d 		Inline graphic
d 		Δ 65:35
hν 53:37
Inline graphic
512c 		Inline graphic
e 		Inline graphic
e 		Δ 58:42
hν 24:76