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. 2016 Aug 3;12:1647–1748. doi: 10.3762/bjoc.12.162

Table 9.

Oxidation of aldimines 118a-f to amides by m-CPBA-BF3·Et2O system.

graphic file with name Beilstein_J_Org_Chem-12-1647-i044.jpg

Compound Imine Product Yield, %

118a C6H5CH=NC6H5 HCON(C6H5)2 82
118b p-Me-C6H4CH=NC6H5 HCONC6H5 p-Me-C6H4 90
118c p-MeO-C6H4CH=NC6H5 HCONC6H5 p-MeO-C6H4 91
118d p-NO2-C6H4CH=NC6H5 p-NO2-C6H4CONHC6H5 71
118e p-NC-C6H4CH=NC6H5 p-NC-C6H4CONHC6H5 79
118f p-F3C-C6H4CH=NC6H5 p-F3C-C6H4CONHC6H5 75