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. 2016 Jul 13;128(33):9748–9752. doi: 10.1002/ange.201603785

Scheme 2.

Scheme 2

Proposed mechanisms of A) ketoreduction by MNMR and B) reduction of an α,β‐unsaturated double bond by IPR. The three‐dimensional nature of the active sites is represented as compounds in the foreground and background shown in black and grey, respectively.