Table 2. Scope of Alkylbis(catecholato)silicates in Photoredox/Ni Cross-Couplinga.
R′ = R″ = Et or R′ = H, R″ = i-Pr.
NMR yield.
Reaction provided comparable yield when no measures were taken to remove oxygen.
Reaction with 3m run on gram scale using 5 mol % [NiCl2(dme)] and dtbbpy with white LEDs.