Table 3. Classification of the Transition Paths in System 2 in Terms of the Residence Time, τb, and the Number of Recrossing Events, Nb, at the Free Energy Barrier (i.e. transition state).
Group | Residence time,τb (ps) | Number of recrossings, Nb | Path type |
---|---|---|---|
A | τb ≤ 0.5 | 2–5 | Fast |
B | 0.5 < τb ≤ 2 | 3–10 | Moderate |
C | 2 < τb ≤ 5 | 5–30 | Moderate |
D | 5 < τb ≤ 8 | 10–40 | Slow |
E | 8 < τb ≤ 10 | 20–65 | Slow |