Table 1. Enantioselective synthesis of MA by chiral-encoded mesoporous platinum.
Electrodes | Ratio of imprinted molecule* | % Enantiomeric excess† |
---|---|---|
(R)-MA imprinted | 0.03 | 5.66 |
0.05 | 10.71 | |
(S)-MA imprinted | 0.03 | −11.73 |
0.05 | −19.05 | |
Destroyed chirality | — | −1.52 |
Commercial racemic mixture | — | −1.01 |
*Weight ratio of MA to H2PtCl6 in the electroplating mixture.
†% Enantiomeric excess (% ee)=(RMA−SMA)/(RMA+SMA) × 100, where RMA and SMA are the HPLC peak areas of (R)-MA and (S)-MA, respectively. The calculated s.e.m. is ±1.13% ee (Supplementary equation (2)).