Table 3.
Analytical bias (% expected concentration) | Imprecision (% coefficient of variation) | ||||
---|---|---|---|---|---|
| |||||
Concentration (μg/L) | Intra-day (mean, N=5) | Inter-day (mean, N=25) | Intra-day (N=5) | Inter-day (N=25) | |
| |||||
THCVCOOH | 3 | 92.7 | 99.3 | 12.7 | 11.6 |
9 | 94.3 | 96.4 | 12.2 | 9.0 | |
80 | 89.1 | 94.5 | 7.1 | 7.9 | |
| |||||
THCCOOH-gluc | 15 | 97.8 | 99.6 | 12.7 | 8.7 |
45 | 98.6 | 101 | 6.4 | 6.5 | |
400 | 88.3 | 90.7 | 5.6 | 6.3 | |
| |||||
THC-gluc | 1.5 | 98.8 | 100 | 14.3 | 13.2 |
4.5 | 101 | 98.1 | 13.0 | 10.0 | |
40 | 93.5 | 92.4 | 8.8 | 9.6 | |
| |||||
THCCOOH | 1.5 | 99.1 | 107 | 12.2 | 9.6 |
4.5 | 104 | 106 | 3.3 | 6.6 | |
80 | 93.7 | 98.1 | 8.4 | 8.1 | |
| |||||
THCAA | 1.5 | 110 | 104 | 5.2 | 11.2 |
4.5 | 98.9 | 100 | 9.1 | 9.9 | |
40 | 97.6 | 99.0 | 10.0 | 13.5 | |
| |||||
11-OH-THC | 1.5 | 110 | 105 | 8.8 | 8.0 |
4.5 | 99.9 | 103 | 8.2 | 6.8 | |
40 | 98.3 | 98.8 | 10.7 | 7.6 | |
| |||||
THCV | 3.0 | 103 | 102 | 11.6 | 8.5 |
9.0 | 102 | 101 | 7.9 | 7.0 | |
80 | 99.0 | 97.7 | 11.6 | 7.8 | |
| |||||
CBD | 1.5 | 106 | 106 | 10.4 | 9.8 |
4.5 | 112 | 109 | 6.7 | 6.5 | |
40 | 100 | 108 | 11.6 | 8.0 | |
| |||||
CBG | 3.0 | 99.6 | 99.8 | 12.0 | 7.6 |
9.0 | 102 | 103 | 7.1 | 6.2 | |
80 | 102 | 103 | 14.1 | 7.9 | |
| |||||
CBN | 1.5 | 114 | 110 | 6.4 | 5.6 |
4.5 | 111 | 110 | 3.8 | 4.8 | |
40 | 101 | 106 | 11.2 | 6.5 | |
| |||||
THC | 1.5 | 105 | 104 | 10.0 | 7.7 |
4.5 | 108 | 103 | 5.0 | 6.8 | |
80 | 96.3 | 99.7 | 11.9 | 7.4 |