Characterization of fibrous nanomaterials. Raman spectra from CNF (A), SWCNT (B), and crocidolite asbestos (C). For the graphite-based materials CNF and SWCNT there are two common features: D band at 1350 cm−1 due to amorphous carbon, impurities, and structural defects and G band at 1590 cm−1 due to high-ordered graphite structure. Low-frequency bands called radial breathing mode (RBM) are seen only in the SWCNT spectrum. The crocidolite spectrum shows specific bands due to metal – oxygen vibrations, below 500 cm−1 and to silicon – oxygen vibrations in the rest of the spectrum.