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. 2016 Sep 13;6:32944. doi: 10.1038/srep32944

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Copyright © 2016, The Author(s)

This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

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(a) Experimentally observed XRD patterns (black curve for H₂DPP-NiPc-COF, red curve for H₂DPP-CuPc-COF, purple curve for ZnDPP-NiPc-COF, sky-blue curve for ZnDPP-CuPc-COF, green curve for CuDPP-NiPc-COF and magenta curve for CuDPP-CuPc-COF) and patterns simulated with the eclipsed AA stacking (blue curve) for H₂DPP-NiPc-COF and with the AB-staggered stacking (orange curve) for H₂DPP-NiPc-COF. (b,c) Views of the unit cell along the z (b) and y (c) axes of H₂DPP-NiPc-COF. (d,e) Views of the AB-staggered unit cell along the z (d) and y (e) axes. Insets in XRD profiles show the enlarged views of the (001) peaks.