Table 7.
Fitting parameters for the density (equation 5), refractive index (equation 6), fluidity (inverse viscosity, equation 8) and ionic conductivity (equation 9) as a function of temperature for the FILs [C2C1py][C4F9CO2] and [N1112(OH)][N(C4F9SO2)2]. Standard deviations (σ) (equation 7) are also shown.
| [C2C1py][C4F9CO2] | ||||
|---|---|---|---|---|
| lnρ / g·cm-3 | A0 = 0.57912 | A1 = -6.8776 · 10-4 | σ = 5.16 · 10-5 | |
| nD | B0 = 1.50875 | B1 = -2.9309 · 10-4 | σ = 3.92 · 10-5 | |
| ϕ / mPa-1·s-1 | ϕ0 = 4.67 | B = 704.80 | T0 =190.54 | σ =1.91 · 10-4 |
| k / mS·cm-1 | k0 = 912.29 | B´ = 852.77 | T0´ = 169.66 | σ = 1.34 · 10-2 |
| [N1112(OH)][N(C4F9SO2)2] | ||||
| lnρ / g·cm-3 | A0 = 0.73393 | A1 = -6.9946 · 10-4 | σ = 5.73 · 10-5 | |
| nD | B0 = 1.45257 | B1 = -2.5625 · 10-4 | σ = 3.16 · 10-5 | |
| ϕ / mPa-1·s-1 | ϕ0 = 1.63 | B = 707.67 | T0 = 217.84 | σ = 7.77 · 10-5 |
| k / mS·cm-1 | k0 =820.51 | B´ = 1275.05 | T0´ = 167.65 | σ = 1.33 · 10-5 |