Table 2.
Experimental TLs (tie-lines) and TLLs (tie-lines length) of ABS composed of C6H5K3O7/C6H8O7 and PEG.
Weight fraction composition / (wt %) | |||||||
---|---|---|---|---|---|---|---|
PEG 400 + K3C6H5O7/C6H8O7 + water | |||||||
pH | [PEG]PEG | [salt]PEG | [PEG]M | [salt]M | [PEG]salt | [salt]salt | TLL |
5.0 | 41.56 | 18.86 | 30.01 | 29.99 | 9.93 | 49.38 | 43.96 |
54.60 | 12.43 | 35.00 | 29.99 | 6.70 | 55.36 | 64.33 | |
6.0 | 42.57 | 14.74 | 29.96 | 25.02 | 14.54 | 37.87 | 37.87 |
45.94 | 13.52 | 29.99 | 29.85 | 8.60 | 51.76 | 53.45 | |
7.0 | 38.35 | 13.82 | 29.72 | 19.92 | 21.39 | 25.80 | 20.76 |
45.44 | 10.79 | 29.75 | 25.20 | 8.13 | 45.03 | 50.63 | |
49.27 | 9.46 | 29.98 | 29.97 | 3.50 | 58.13 | 66.80 | |
36.00 | 15.02 | 25.28 | 24.75 | 13.50 | 35.45 | 30.38 | |
48.82 | 9.61 | 25.22 | 34.66 | 3.03 | 60.09 | 68.15 | |
67.33 | 5.10 | 40.08 | 30.01 | 2.09 | 64.73 | 88.38 | |
8.0 | 53.36 | 4.32 | 25.06 | 24.99 | 1.09 | 42.50 | 64.72 |
64.69 | 2.19 | 30.13 | 29.84 | 0.06 | 53.90 | 82.77 | |
PEG + K3C6H5O7/C6H8O7 + water at pH 7.0 | |||||||
PEG | [PEG]PEG | [salt]PEG | [PEG]M | [salt]M | [PEG]salt | [salt]salt | TLL |
600 | 73.68 | 3.16 | 30.17 | 25.92 | 1.19 | 41.08 | 81.81 |
74.70 | 3.04 | 30.13 | 30.33 | 0.21 | 48.66 | 87.35 | |
63.64 | 4.57 | 29.98 | 19.99 | 6.19 | 30.88 | 63.18 | |
60.27 | 5.15 | 25.01 | 25.02 | 2.14 | 37.89 | 66.71 | |
86.69 | 1.87 | 35.05 | 24.96 | 1.47 | 39.96 | 93.34 | |
1000 | 57.95 | 5.45 | 29.95 | 25.09 | 0.05 | 46.04 | 70.70 |
59.43 | 5.21 | 29.94 | 30.03 | 0.00 | 55.16 | 77.63 | |
46.49 | 7.64 | 29.97 | 20.06 | 0.04 | 46.87 | 60.80 | |
58.47 | 5.37 | 35.05 | 25.03 | 0.00 | 54.44 | 76.33 | |
41.72 | 8.79 | 25.04 | 25.00 | 0.01 | 49.29 | 58.13 |