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. Author manuscript; available in PMC: 2017 Jan 15.
Published in final edited form as: Science. 2016 Jun 23;353(6296):279–283. doi: 10.1126/science.aag0209

Figure 3. Metallaphotoredox-catalyzed amination: amine and arene scope.

Figure 3

For each entry number (in boldface), data are reported as percent isolated yield. R, H, alkyl, or aryl substrate; Y, C, CH, or N; X, CI or Br; DABCO, 1,4-diazabicyclo[2.2.2]octane; MTBD, 7-methyl-1,5,7-triazabicyclo [4.4.0]dec-5-ene; LED, light-emitting diode; Me, methyl; n-pent, n-pentyl; Boc, tert-butoxycarbonyl. *Run at ambient temperature. †Reaction heated to 55 °C. ‡DMSO used as solvent. §MTBD used as base. ‖0.002 mol% 1 used. ¶10 mol% pyrrolidine included. #See Supplementary Materials for details.