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. Author manuscript; available in PMC: 2017 May 25.
Published in final edited form as: J Am Chem Soc. 2016 May 17;138(20):6404–6407. doi: 10.1021/jacs.6b03465

Table 3.

Silylation of Unactivated Tertiary Alkyl Bromides: Scope

graphic file with name nihms815606u4.jpg
entry substrate yield (%)a
1 graphic file with name nihms815606t11.jpg 70
2 graphic file with name nihms815606t12.jpg 54
3 graphic file with name nihms815606t13.jpg 49
4 graphic file with name nihms815606t14.jpg 70
5 graphic file with name nihms815606t15.jpg 70
6b graphic file with name nihms815606t16.jpg 74
a

Yield of purified product (average of two experiments).

b

Catalyst loading: 2.0 mol% NiBr2·diglyme.