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(A) TEM images of AuNPs of average core diameters 1.5 nm, 4 nm, and 14 nm. The scale bar length is 5 nm for AuNP1.5 and AuNP4 images and 20 nm for the image of AuNP14. (B) EDAX spectra of AuNP1.5 before (left) and after replacing PPh3 with MSA.