Table 2. 13C NMR spectroscopic data for compounds 1–8a.
No. | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 |
---|---|---|---|---|---|---|---|---|
1 | 136.6 qC | 109.2 qC | 87.8 qC | 214.5 qC | 198.7 qC | 199.3 qC | 198.6 qC | 32.6 CH2 |
2 | 36.2 CH | 55.0 CH | 46.3 CH | 48.6 CH | 130.4 qC | 129.2 qC | 128.4 qC | 25.0 CH2 |
3 | 73.7 CH | 76.3 CH | 75.8 CH | 77.1 CH | 160.9 CH | 158.3 CH | 161.9 CH | 75.9 CH |
4 | 37.1 qC | 39.4 qC | 45.2 qC | 39.4 qC | 36.6 qC | 36.8 qC | 36.8 qC | 36.9 qC |
5 | 40.4 CH | 41.7 CH | 42.5 CH | 42.4 CH | 45.2 CH | 43.0 CH | 45.2 CH | 41.8 CH |
6 | 32.7 CH2 | 33.6 CH2 | 71.6 CH | 33.3 CH2 | 34.8 CH2 | 34.7 CH2 | 34.6 CH2 | 23.2 CH2 |
7 | 174.5 qC | 174.0 qC | 170.0 qC | 174.1 qC | 173.5 qC | 173.6 qC | 173.4 qC | 75.3 CH |
8 | 75.5 qC | 89.6 qC | 73.3 qC | 62.7 qC | 201.0 qC | 197.8 qC | 80.1 qC | 42.2 qC |
9 | 98.2 qC | 99.8 qC | 31.0 CH | 54.4 CH | 79.8 qC | 172.8 qC | 208.2/208.0 qC | 43.0 CH |
10 | 119.7 qC | 36.5 CH | 47.2 qC | 48.2 qC | 43.2 CH | 45.6 CH | 42.8 CH | 37.4 qC |
11 | 28.2 CH2 | 33.0 CH2 | 28.8 CH2 | 18.5 CH2 | 29.5 CH2 | 29.4 CH2 | 32.9 CH2 | 16.2 CH2 |
12 | 25.5 CH2 | 27.1 CH2 | 71.0 CH | 33.1 CH2 | 28.6 CH2 | 29.8 CH2 | 25.6 CH2 | 33.8 CH2 |
13 | 38.3 qC | 36.1 qC | 39.3 qC | 40.3 qC | 41.5 qC | 41.4 qC | 38.6/38.5 qC | 46.6 qC |
14 | 163.7 qC | 35.6 CH | 46.4 CH | 71.8 qC | 156.6 qC | 158.9 qC | 162.5 qC | 159.6 qC |
15 | 117.7 CH | 29.0 CH2 | 28.0 CH2 | 40.8 CH2 | 121.2 CH | 124.4 CH | 117.7 CH | 118.0 CH |
16 | 165.5 qC | 171.2 qC | 169.7 qC | 169.5 qC | 163.4 qC | 163.4 qC | 164.5/164.3 qC | 34.8 CH2 |
17 | 81.1 CH | 79.4 CH | 76.8 CH | 78.4 CH | 81.4 CH | 78.5 CH | 78.2/77.9 CH | 58.1 CH |
18 | 18.8 CH3 | 24.4 CH3 | 18.8 CH3 | 20.1 CH3 | 18.6 CH3 | 20.4 CH3 | 18.4/18.3 CH3 | 19.3 CH3 |
19 | 12.8 CH3 | 10.8 CH3 | 22.6 CH3 | 16.4 CH3 | 12.2 CH3 | 11.7 CH3 | 11.6 CH3 | 15.4 CH3 |
20 | 119.7 qC | 120.9 qC | 120.7 qC | 120.1 qC | 119.2 qC | 119.6 qC | 132.9 qC | 37.5 CH |
21 | 141.2 CH | 140.8 CH | 140.4 CH | 141.2 CH | 141.4 CH | 141.6 CH | 169.1/168.8 qC | 72.6 CH2 |
22 | 109.8 CH | 109.9 CH | 109.1 CH | 110.4 CH | 109.7 CH | 109.8 CH | 150.4/149.7 CH | 34.1 CH2 |
23 | 142.9 CH | 143.3 CH | 143.9 CH | 142.9 CH | 143.3 CH | 143.4 CH | 97.4/96.7 CH | 176.8 qC |
28 | 24.8 CH3 | 24.4 CH3 | 15.6 CH3 | 23.0 CH3 | 20.6 CH3 | 20.1 CH3 | 27.8 CH3 | 21.9 CH3 |
29 | 20.1 CH3 | 20.9 CH3 | 41.0 CH2 | 20.7 CH3 | 28.0 CH3 | 28.2 CH3 | 20.6 CH3 | 28.0 CH3 |
30 | 68.9 CH | 71.3 CH | 69.7 CH | 62.8 CH | 66.8 CH | 41.3 CH2 | 67.8 CH | 27.5 CH3 |
7-OMe | 52.0 CH3 | 51.9 CH3 | 53.0 CH3 | 52.4 CH3 | 52.0 CH3 | 52.0 CH3 | 52.0 CH3 | |
9-OMe | 51.8 CH3 | |||||||
7-OAc | 21.3 CH3 | |||||||
170.4 qC | ||||||||
1-OAc | 21.0 CH3 | |||||||
168.4 qC | ||||||||
3-OAc | 21.2 CH3 | 21.1 CH3 | ||||||
169.8 qC | 169.4 qC | |||||||
6-OAc | 21.0 CH3 | |||||||
169.6 qC | ||||||||
12-OAc | 22.1 CH3 | |||||||
169.7 qC | ||||||||
30-OAc | 20.7 CH3 | 20.9 CH3 | 21.4 CH3 | 21.0 CH3 | ||||
170.5 qC | 170.2 qC | 170.7 qC | 169.9/169.8 qC | |||||
1′ | 167.3 qC | 167.0 qC | 165.7 qC | |||||
2′ | 128.7 qC | 127.4 qC | 127.8 qC | |||||
3′ | 137.2 CH | 140.4 CH | 138.9 CH | |||||
4′ | 14.5 CH3 | 14.8 CH3 | 14.6 CH3 | |||||
5′ | 12.1 CH3 | 12.3 CH3 | 12.0 CH3 |
aSpectra measured at 100 MHz in CDCl3.